MARCELLO GENNARI
Chargé de recherches
Affiliation
Centre national de la recherche scientifique
Équipe de recherche
DCM-CIRE
Domaines de recherche
Bio-inspired Inorganic Chemistry
Disciplines scientifiques
Chimie organique, minérale, industrielle
Habilitation à diriger des recherches
from 17/01/2017 to 17/01/2017
Thèse
Scorpionate ligands and surroundings. Coordination properties – Solution studies
sous la direction de L. Marchio', M. Lanfranchi
from 01/01/2005 to 06/03/2008
sous la direction de L. Marchio', M. Lanfranchi
from 01/01/2005 to 06/03/2008
ORCID
Ghosh, A. C., Duboc C., & Gennari M.
(2021). Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes.
Coordination Chemistry Reviews. 428, 213606.
Ahmed, M. Estak, Saha D., Wang L., Gennari M., Dey S. Ghosh, Artero V., et al.
(2021). An [FeFe]-Hydrogenase Mimic Immobilized through Simple Physiadsorption and Active for Aqueous H2 Production.
ChemElectroChem. 8, 1674-1677.
Wang, L., Gennari M., Barrozo A., Fize J., Philouze C., Demeshko S., et al.
(2020). Role of the Metal Ion in Bio-Inspired Hydrogenase Models: Investigation of a Homodinuclear FeFe Complex vs Its Heterodinuclear NiFe Analogue.
ACS Catalysis. 10, 177-186.
Wang, L., Gennari M., Barrozo A., Fize J., Philouze C., Demeshko S., et al.
(2020). Role of the Metal Ion in Bio-Inspired Hydrogenase Models: Investigation of a Homodinuclear FeFe Complex vs Its Heterodinuclear NiFe Analogue.
ACS Catalysis. 10, 177-186.
Wang, L., Gennari M., Reinhard F. G. Cantú, Padamati S. K., Philouze C., Flot D., et al.
(2020). O2 Activation by Non-Heme Thiolate-Based Dinuclear Fe Complexes.
Inorganic Chemistry. 59, 3249-3259.
Gennari, M., & Duboc C.
(2020). Bio-inspired, Multifunctional Metal–Thiolate Motif: From Electron Transfer to Sulfur Reactivity and Small-Molecule Activation.
Accounts of Chemical Research. 53, 2753-2761.
Wang, L., Gennari M., Reinhard F. G. Cantú, Gutiérrez J., Morozan A., Philouze C., et al.
(2019). A Non-Heme Diiron Complex for (Electro)catalytic Reduction of Dioxygen: Tuning the Selectivity through Electron Delivery.
Journal of the American Chemical Society. 141, 8244-8253.
Wang, L., Gennari M., Cantù F. G., Gutiérrez J., Morozan A., Philouze C., et al.
(2019). A Non-Heme Diiron Complex for (Electro)catalytic Reduction of Dioxygen: Tuning the Selectivity through Electron Delivery.
Journal of the American Chemical Society. 141, 8244-8253.
Wang, L., Reinhard F. G. Cantú, Philouze C., Demeshko S., de Visser S. P., Meyer F., et al.
(2018). Solvent- and Halide-Induced (Inter)conversion between Iron(II)-Disulfide and Iron(III)-Thiolate Complexes.
Chemistry – A European Journal. 24, 11973-11982.
Brazzolotto, D., Wang L., Tang H., Gennari M., Queyriaux N., Philouze C., et al.
(2018). Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process.
ACS Catalysis. 8, 10658-10667.
Ahmed, M. Estak, Chattopadhyay S., Wang L., Brazzolotto D., Pramanik D., Aldakov D., et al.
(2018). Hydrogen Evolution from Aqueous Solutions Mediated by a Heterogenized [NiFe]-Hydrogenase Model: Low pH Enables Catalysis through an Enzyme-Relevant Mechanism.
Angewandte Chemie International Edition. 57, 16001-16004.
Wang, L., Matija Z., Filip V., Serhiy D., Philouze C., Molton F., et al.
(2018). Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes.
Chemistry – A European Journal. 24, 5091-5094.
Ahmed, M. Estak, Chattopadhyay S., Wang L., Brazzolotto D., Pramanik D., Aldakov D., et al.
(2018). Hydrogen Evolution from Aqueous Solutions Mediated by a Heterogenized [NiFe]-Hydrogenase Model: Low pH Enables Catalysis through an Enzyme-relevant Mechanism..
Angew. Chemie, Int. Ed.. 57, 16001–16004.
Brazzolotto, D., Wang L., Tang H., Gennari M., Queyriaux N., Philouze C., et al.
(2018). Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process..
ACS Catal.. 8, 10658–10667.
Wang, L., Reinhard F. G. Cantú, Philouze C., Demeshko S., de Visser S. P., Meyer F., et al.
(2018). Solvent- and Halide-Induced (Inter)conversion between Iron(II)-Disulfide and Iron(III)-Thiolate Complexes..
Chem. - A Eur. J.. 24, 11973–11982.
Wang, L., Zlatar M., Vlahovic F., Demeshko S., Philouze C., Molton F., et al.
(2018). Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes..
Chem. - A Eur. J.. 24, 5091–5094.
Roux, Y., Duboc C., & Gennari M.
(2017). Molecular Catalysts for N2 Reduction: State of the Art, Mechanism, and Challenges.
ChemPhysChem. 18, 2606-2617.
Balestri, D., Roux Y., Mattarozzi M., Mucchino C., Heux L., Brazzolotto D., et al.
(2017). Heterogenization of a [NiFe] Hydrogenase Mimic through Simple and Efficient Encapsulation into a Mesoporous MOF.
Inorganic Chemistry. 56, 14801-14808.
Roux, Y., Duboc C., & Gennari M.
(2017). Molecular Catalysts for N2 Reduction: State of the Art, Mechanism, and Challenges..
ChemPhysChem. 18, 2606–2617.
Brazzolotto, D., Reinhard F. G. Cantú, Smith-Jones J., Retegan M., Amidani L., Faponle A. S., et al.
(2017). A High-Valent Non-Heme μ-Oxo Manganese(IV) Dimer Generated from a Thiolate-Bound Manganese(II) Complex and Dioxygen..
Angew. Chemie, Int. Ed.. 56, 8211–8215.
Balestri, D., Roux Y., Mattarozzi M., Mucchino C., Heux L., Brazzolotto D., et al.
(2017). Heterogenization of a [NiFe] Hydrogenase Mimic through Simple and Efficient Encapsulation into a Mesoporous MOF..
Inorg. Chem.. 56, 14801–14808.
Brazzolotto, D., Gennari M., Yu S., Pécaut J., Rouzières M., Clérac R., et al.
(2016). An Experimental and Theoretical Investigation on Pentacoordinated Cobalt(III) Complexes with an Intermediate S=1 Spin State: How Halide Ligands Affect their Magnetic Anisotropy..
Chem. - A Eur. J.. 22, 925–933.
Brazzolotto, D., Gennari M., Queyriaux N., Simmons T. R., Pécaut J., Demeshko S., et al.
(2016). Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase..
Nat. Chem.. 8, 1054–1060.
Hall, N., Orio M., Gennari M., Wills C., Molton F., Philouze C., et al.
(2016). Multifrequency cw-EPR and DFT Studies of an Apparent Compressed Octahedral Cu(II) Complex..
Inorg. Chem.. 55, 1497–1504.
Martin-Diaconescu, V., Gennari M., Gerey B., Tsui E., Kanady J., Tran R., et al.
(2015). Ca K-Edge XAS as a Probe of Calcium Centers in Complex Systems..
Inorg. Chem.. 54, 1283–1292.
Beckwith, M. A., Ames W., Vila F. D., Krewald V., Pantazis D. A., Mantel C., et al.
(2015). How Accurately Can Extended X-ray Absorption Spectra Be Predicted from First Principles? Implications for Modeling the Oxygen-Evolving Complex in Photosystem II..
J. Am. Chem. Soc.. 137, 12815–12834.
Gennari, M., Brazzolotto D., Pécaut J., Cherrier M. V., Pollock C. J., DeBeer S., et al.
(2015). Dioxygen Activation and Catalytic Reduction to Hydrogen Peroxide by a Thiolate-Bridged Dimanganese(II) Complex with a Pendant Thiol..
J. Am. Chem. Soc.. 137, 8644–8653.
Martinez-Perinan, E., Gennari M., Revenga-Parra M., Abad J. M., Mateo-Marti E., Pariente F., et al.
(2015). Highly dense nickel hydroxide nanoparticles catalyst electrodeposited from a novel Ni(II) paddle-wheel complex..
J. Catal.. 329, 22–31.
Gerey, B., Gennari M., Gouré E., Pécaut J., Blackman A., Pantazis D. A., et al.
(2015). Calcium and heterometallic manganese-calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations..
Dalt. Trans.. 44, 12757–12770.
Castillo, C. E., Gennari M., Stoll T., Fortage J., Deronizer A., Collomb M-N., et al.
(2015). Visible Light-Driven Electron Transfer from a Dye-Sensitized p-Type NiO Photocathode to a Molecular Catalyst in Solution: Toward NiO-Based Photoelectrochemical Devices for Solar Hydrogen Production..
J. Phys. Chem. C. 119, 5806–5818.
Gennari, M., Givaja G., Castillo O., Hermosilla L., Gómez-García C. J., Duboc C., et al.
(2014). On the Road to MM'X Polymers: Redox Properties of Heterometallic Ni···Pt Paddlewheel Complexes..
Inorg. Chem.. 53, 10553–10562.
Stoll, T., Gennari M., Fortage J., Castillo C. E., Rebarz M., Sliwa M., et al.
(2014). An efficient RuII-RhIII-RuII polypyridyl photocatalyst for visible-light-driven hydrogen production in aqueous solution..
Angew. Chemie, Int. Ed.. 53, 1654–1658.
Gennari, M., Legalite F., Zhang L., Pellegrin Y., Blart E., Fortage J., et al.
(2014). Long-Lived Charge Separated State in NiO-Based p-Type Dye-Sensitized Solar Cells with Simple Cyclometalated Iridium Complexes..
J. Phys. Chem. Lett.. 5, 2254–2258.
Gennari, M., Gerey B., Hall N., Pécaut J., Collomb M-N., Rouzières M., et al.
(2014). A Bio-Inspired Switch Based on Cobalt(II) Disulfide/Cobalt(III) Thiolate Interconversion..
Angew. Chemie, Int. Ed.. 53, 5318–5321.
Stoll, T., Gennari M., Serrano I., Fortage J., Chauvin J., Odobel F., et al.
(2013). [RhIII(dmbpy)2Cl2]+ as a Highly Efficient Catalyst for Visible-Light-Driven Hydrogen Production in Pure Water: Comparison with Other Rhodium Catalysts..
Chem. - A Eur. J.. 19, 782–792.
Gennari, M., Gerey B., Hall N., Pécaut J., Vezin H., Collomb M-N., et al.
(2012). Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex - the reactivity toward S-alkylation: an experimental and theoretical study..
Dalt. Trans.. 41, 12586–12594.
Gennari, M., Pécaut J., Collomb M-N., & Duboc C.
(2012). A copper thiolate centre for electron transfer: mononuclear vs. dinuclear complexes..
Dalt. Trans.. 41, 3130–3133.
Gennari, M., Retegan M., DeBeer S., Pécaut J., Neese F., Collomb M-N., et al.
(2011). Experimental and Computational Investigation of Thiolate Alkylation in NiII and ZnII Complexes: Role of the Metal on the Sulfur Nucleophilicity..
Inorg. Chem.. 50, 10047–10055.
Gennari, M., Orio M., Pécaut J., Bothe E., Neese F., Collomb M-N., et al.
(2011). Influence of Mixed Thiolate/Thioether versus Dithiolate Coordination on the Accessibility of the Uncommon +I and +III Oxidation States for the Nickel Ion: An Experimental and Computational Study..
Inorg. Chem.. 50, 3707–3716.
Gennari, M., Pécaut J., DeBeer S., Neese F., Collomb M-N., & Duboc C.
(2011). A Fully Delocalized Mixed-Valence Bis-$μ$(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center..
Angew. Chemie, Int. Ed.. 50, 5662–5666, S5662/1–S5662/16.
I received my PhD in chemical sciences from the University of Parma in 2008 under the supervision of Professors Luciano Marchio´ and Maurizio Lanfranchi. Following postdoctoral positions at the University of Grenoble and at the Autonoma University of Madrid, I joined the Département de Chimie Moléculaire of the University of Grenoble Alpes in 2013, where I am now CNRS junior researcher. My current research interests focus on bio-inspired transition metal complexes for the activation of small molecules.
