CAROLE DUBOC
Directrice de recherche (CNRS)
Affiliation
Centre national de la recherche scientifique
Équipe de recherche
DCM-CIRE
Domaines de recherche
BioInorganic Chemistry - Molecular Catalysis (homogeneous & heterogeneous) - O2 activation & reduction - H2 production - CO2 reduction - Mechanism - Electrocatalysis - Thiolate-based ligands -Magnetic properties
Disciplines scientifiques
Chimie théorique, physique, analytique
Habilitation à diriger des recherches
2005
Responsabilités
2022- Chair of the Cross-Disciplinary Project, IDEX Grenoble, DefiCO2
2021- Chair of ARCANE Excellence Laboratory Network (LABEX) for bio-driven chemistry
2020- Associate Editor of JACS Au
2019- Scientific board member of the EUR "Chemistry, Biology & Health" of the UGA
2013- Scientific manager of the EPR platform of the DCM
Enseignement
Responsable UE BioInorganic Chemistry, Health & Energy, Master II Chemistry
Responsable Master II Chemistry for Life Science
Responsable Master II Chemistry for Life Science
Sun, L., Duboc C., & Shen K.
(2022). Bioinspired Molecular Electrocatalysts for H2 Production: Chemical Strategies.
ACS Catalysis. 12, 9159-9170.
Flitsch, S., Duboc C., & Bonnet S.
(2022). New Chemical Tools for Diagnosis and Treatment of Cancer.
JACS Au. 2, 1018-1019.
Sun, L., Adam S. M., Mokdad W., David R., Milet A., Artero V., et al.
(2022). A bio-inspired heterodinuclear hydrogenase CoFe complex.
Faraday Discuss.. 234, 34-41.
Ahmed, M. Estak, Saha D., Wang L., Gennari M., Dey S. Ghosh, Artero V., et al.
(2021). An [FeFe]-Hydrogenase Mimic Immobilized through Simple Physiadsorption and Active for Aqueous H2 Production.
ChemElectroChem. 8, 1674-1677.
Domergue, J., Guinard P., Douillard M., Pécaut J., Proux O., Lebrun C., et al.
(2021). A Bioinspired NiII Superoxide Dismutase Catalyst Designed on an ATCUN-like Binding Motif.
Inorganic Chemistry. 60, 12772-12780.
Domergue, J.., Guinard P.., Douillard M.., Pecaut J.., Proux O.., Lebrun C.., et al.
(2021). A Bioinspired Ni(II) Superoxide Dismutase Catalyst Designed on an ATCUN-like Binding Motif.
Inorg. Chem.. 61(17),
Sun, L., Adam S. M., Mokdad W., David R., Milet A., Artero V., et al.
(2021). A bio-inspired heterodinuclear CoFe complex of the hydrogenases.
Faraday Discuss.. -.
Ghosh, A. C., Duboc C., & Gennari M.
(2021). Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes.
Coordination Chemistry Reviews. 428, 213606.
Wang, L., Gennari M., Barrozo A., Fize J., Philouze C., Demeshko S., et al.
(2020). Role of the Metal Ion in Bio-Inspired Hydrogenase Models: Investigation of a Homodinuclear FeFe Complex vs Its Heterodinuclear NiFe Analogue.
ACS Catalysis. 10, 177-186.
Wang, L., Gennari M., Barrozo A., Fize J., Philouze C., Demeshko S., et al.
(2020). Role of the Metal Ion in Bio-Inspired Hydrogenase Models: Investigation of a Homodinuclear FeFe Complex vs Its Heterodinuclear NiFe Analogue.
ACS Catalysis. 10, 177-186.
Wang, L., Gennari M., Reinhard F. G. Cantú, Padamati S. K., Philouze C., Flot D., et al.
(2020). O2 Activation by Non-Heme Thiolate-Based Dinuclear Fe Complexes.
Inorganic Chemistry. 59, 3249-3259.
Mangue, J., Gondre C., Pécaut J., Duboc C., Ménage S., & Torelli S.
(2020). Controlled O2 reduction at a mixed-valent (II,I) Cu2S core.
Chem. Commun.. 56, 9636-9639.
Gennari, M., & Duboc C.
(2020). Bio-inspired, Multifunctional Metal–Thiolate Motif: From Electron Transfer to Sulfur Reactivity and Small-Molecule Activation.
Accounts of Chemical Research. 53, 2753-2761.
Ahmed, M. Estak, Adam S., Saha D., Fize J., Artero V., Dey A., et al.
(2020). Repurposing a Bio-Inspired NiFe Hydrogenase Model for CO2 Reduction with Selective Production of Methane as the Unique C-Based Product.
ACS Energy Letters. 5, 3837-3842.
Wang, L., Gennari M., Reinhard F. G. Cantú, Gutiérrez J., Morozan A., Philouze C., et al.
(2019). A Non-Heme Diiron Complex for (Electro)catalytic Reduction of Dioxygen: Tuning the Selectivity through Electron Delivery.
Journal of the American Chemical Society. 141, 8244-8253.
Wang, L., Gennari M., Cantù F. G., Gutiérrez J., Morozan A., Philouze C., et al.
(2019). A Non-Heme Diiron Complex for (Electro)catalytic Reduction of Dioxygen: Tuning the Selectivity through Electron Delivery.
Journal of the American Chemical Society. 141, 8244-8253.
Xémard, M., Cordier M., Molton F., Duboc C., Le Guennic B., Maury O., et al.
(2019). Divalent Thulium Crown Ether Complexes with Field-Induced Slow Magnetic Relaxation.
Inorganic Chemistry. 58, 2872-2880.
Domergue, J., Pécaut J., Proux O., Lebrun C., Gateau C., Le Goff A., et al.
(2019). Mononuclear Ni(II) Complexes with a S3O Coordination Sphere Based on a Tripodal Cysteine-Rich Ligand: pH Tuning of the Superoxide Dismutase Activity.
Inorganic Chemistry. 58, 12775-12785.
Darmanović, D., Shcherbakov I. N., Duboc C., Spasojević V., Hanžel D., Anđelković K., et al.
(2019). Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone.
The Journal of Physical Chemistry C. 123, 31142-31155.
Wang, L., Matija Z., Filip V., Serhiy D., Philouze C., Molton F., et al.
(2018). Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes.
Chemistry – A European Journal. 24, 5091-5094.
Ahmed, M. Estak, Chattopadhyay S., Wang L., Brazzolotto D., Pramanik D., Aldakov D., et al.
(2018). Hydrogen Evolution from Aqueous Solutions Mediated by a Heterogenized [NiFe]-Hydrogenase Model: Low pH Enables Catalysis through an Enzyme-relevant Mechanism..
Angew. Chemie, Int. Ed.. 57, 16001–16004.
Jennah, O., Beniazza R., Lozach C., Jardel D., Molton F., Duboc C., et al.
(2018). Photoredox Catalysis at Copper(II) on Chitosan: Application to Photolatent CuAAC..
Adv. Synth. Catal.. 360, 4615–4624.
Brazzolotto, D., Wang L., Tang H., Gennari M., Queyriaux N., Philouze C., et al.
(2018). Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process..
ACS Catal.. 8, 10658–10667.
Chen, J., Draksharapu A., Angelone D., Unjaroen D., Padamati S. K., Hage R., et al.
(2018). H2O2 Oxidation by FeIII-OOH Intermediates and Its Effect on Catalytic Efficiency..
ACS Catal.. 8, 9665–9674.
Wang, L., Reinhard F. G. Cantú, Philouze C., Demeshko S., de Visser S. P., Meyer F., et al.
(2018). Solvent- and Halide-Induced (Inter)conversion between Iron(II)-Disulfide and Iron(III)-Thiolate Complexes.
Chemistry – A European Journal. 24, 11973-11982.
Wang, L., Reinhard F. G. Cantú, Philouze C., Demeshko S., de Visser S. P., Meyer F., et al.
(2018). Solvent- and Halide-Induced (Inter)conversion between Iron(II)-Disulfide and Iron(III)-Thiolate Complexes..
Chem. - A Eur. J.. 24, 11973–11982.
Brazzolotto, D., Wang L., Tang H., Gennari M., Queyriaux N., Philouze C., et al.
(2018). Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process.
ACS Catalysis. 8, 10658-10667.
Wang, L., Zlatar M., Vlahovic F., Demeshko S., Philouze C., Molton F., et al.
(2018). Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes..
Chem. - A Eur. J.. 24, 5091–5094.
Ahmed, M. Estak, Chattopadhyay S., Wang L., Brazzolotto D., Pramanik D., Aldakov D., et al.
(2018). Hydrogen Evolution from Aqueous Solutions Mediated by a Heterogenized [NiFe]-Hydrogenase Model: Low pH Enables Catalysis through an Enzyme-Relevant Mechanism.
Angewandte Chemie International Edition. 57, 16001-16004.
Xémard, M., Jaoul A., Cordier M., Molton F., Cador O., Le Guennic B., et al.
(2017). Divalent Thulium Triflate: A Structural and Spectroscopic Study..
Angew. Chemie, Int. Ed.. 56, 4266–4271.
Balestri, D., Roux Y., Mattarozzi M., Mucchino C., Heux L., Brazzolotto D., et al.
(2017). Heterogenization of a [NiFe] Hydrogenase Mimic through Simple and Efficient Encapsulation into a Mesoporous MOF..
Inorg. Chem.. 56, 14801–14808.
Marcon, J., Mortha G., Marlin N., Molton F., Duboc C., & Burnet A..
(2017). New insights into the decomposition mechanism of chlorine dioxide at alkaline pH..
Holzforschung. 71, 599–610.
Roux, Y., Duboc C., & Gennari M.
(2017). Molecular Catalysts for N2 Reduction: State of the Art, Mechanism, and Challenges.
ChemPhysChem. 18, 2606-2617.
Balestri, D., Roux Y., Mattarozzi M., Mucchino C., Heux L., Brazzolotto D., et al.
(2017). Heterogenization of a [NiFe] Hydrogenase Mimic through Simple and Efficient Encapsulation into a Mesoporous MOF.
Inorganic Chemistry. 56, 14801-14808.
Corona, T., Padamati S. K., Acuña-Parés F., Duboc C., Browne W. R., & Company A..
(2017). Trapping of superoxido cobalt and peroxido dicobalt species formed reversibly from CoII and O2..
Chem. Commun. (Cambridge, United Kingdom). 53, 11782–11785.
Roux, Y., Duboc C., & Gennari M.
(2017). Molecular Catalysts for N2 Reduction: State of the Art, Mechanism, and Challenges..
ChemPhysChem. 18, 2606–2617.
Brazzolotto, D., Reinhard F. G. Cantú, Smith-Jones J., Retegan M., Amidani L., Faponle A. S., et al.
(2017). A High-Valent Non-Heme μ-Oxo Manganese(IV) Dimer Generated from a Thiolate-Bound Manganese(II) Complex and Dioxygen..
Angew. Chemie, Int. Ed.. 56, 8211–8215.
Duboc, C.
(2016). Determination and prediction of the magnetic anisotropy of Mn ions..
Chem. Soc. Rev.. 45, 5834–5847.
Brazzolotto, D., Gennari M., Yu S., Pécaut J., Rouzières M., Clérac R., et al.
(2016). An Experimental and Theoretical Investigation on Pentacoordinated Cobalt(III) Complexes with an Intermediate S=1 Spin State: How Halide Ligands Affect their Magnetic Anisotropy..
Chem. - A Eur. J.. 22, 925–933.
Brazzolotto, D., Gennari M., Queyriaux N., Simmons T. R., Pécaut J., Demeshko S., et al.
(2016). Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase..
Nat. Chem.. 8, 1054–1060.
Zlatar, M., Gruden M., Vassilyeva O. Yu, Buvaylo E. A., Ponomarev A. N., Zvyagin S. A., et al.
(2016). Origin of the Zero-Field Splitting in Mononuclear Octahedral MnIV Complexes: A Combined Experimental and Theoretical Investigation..
Inorg. Chem.. 55, 1192–1201.
Hall, N., Orio M., Gennari M., Wills C., Molton F., Philouze C., et al.
(2016). Multifrequency cw-EPR and DFT Studies of an Apparent Compressed Octahedral Cu(II) Complex..
Inorg. Chem.. 55, 1497–1504.
Lannes, A., Suffren Y., Tommasino J. Bernard, Chiriac R., Toche F., Khrouz L., et al.
(2016). Room Temperature Magnetic Switchability Assisted by Hysteretic Valence Tautomerism in a Layered Two-Dimensional Manganese-Radical Coordination Framework..
J. Am. Chem. Soc.. 138, 16493–16501.
Gerey, B., Gennari M., Gouré E., Pécaut J., Blackman A., Pantazis D. A., et al.
(2015). Calcium and heterometallic manganese-calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations..
Dalt. Trans.. 44, 12757–12770.
Martin-Diaconescu, V., Gennari M., Gerey B., Tsui E., Kanady J., Tran R., et al.
(2015). Ca K-Edge XAS as a Probe of Calcium Centers in Complex Systems..
Inorg. Chem.. 54, 1283–1292.
Beniazza, R., Bayo N., Molton F., Duboc C., Massip S., McClenaghan N., et al.
(2015). Effective ascorbate-free and photolatent click reactions in water using a photoreducible copper(II)-ethylenediamine precatalyst..
Beilstein J. Org. Chem.. 11, 1950–1959.
Beckwith, M. A., Ames W., Vila F. D., Krewald V., Pantazis D. A., Mantel C., et al.
(2015). How Accurately Can Extended X-ray Absorption Spectra Be Predicted from First Principles? Implications for Modeling the Oxygen-Evolving Complex in Photosystem II..
J. Am. Chem. Soc.. 137, 12815–12834.
Gennari, M., Brazzolotto D., Pécaut J., Cherrier M. V., Pollock C. J., DeBeer S., et al.
(2015). Dioxygen Activation and Catalytic Reduction to Hydrogen Peroxide by a Thiolate-Bridged Dimanganese(II) Complex with a Pendant Thiol..
J. Am. Chem. Soc.. 137, 8644–8653.
Beniazza, R., Molton F., Duboc C., Tron A., McClenaghan N. D., Lastécouères D., et al.
(2015). Copper(I)-photocatalyzed trifluoromethylation of alkenes..
Chem. Commun. (Cambridge, United Kingdom). 51, 9571–9574.
Bach, M., Roy S., Sarkar B., Bubrin M., Niemeyer M., Fiedler J., et al.
(2015). Heterotetranuclear Complexes of Reduced and Non-reduced Bridging 1,2,4,5-Tetrazine Ligands with 1,1'-Bis(diphenylphosphanyl)-ferrocene-copper(I)..
Zeitschrift fuer Anorg. und Allg. Chemie. 641, 327–331.
Petit-Haertlein, I., Rome K., de Rosny E., Molton F., Duboc C., Gueguen E., et al.
(2015). Biophysical and physiological characterization of ZraP from Escherichia coli, the periplasmic accessory protein of the atypical ZraSR two-component system..
Biochem. J.. 472, 205–216.
Gennari, M., Givaja G., Castillo O., Hermosilla L., Gómez-García C. J., Duboc C., et al.
(2014). On the Road to MM'X Polymers: Redox Properties of Heterometallic Ni···Pt Paddlewheel Complexes..
Inorg. Chem.. 53, 10553–10562.
Beniazza, R., Lambert R., Harmand L., Molton F., Duboc C., Denisov S., et al.
(2014). Sunlight-Driven Copper-Catalyst Activation Applied to Photolatent Click Chemistry..
Chem. - A Eur. J.. 20, 13181–13187.
Rich, J., Manrique E., Molton F., Duboc C., Collomb M-N., Rodriguez M., et al.
(2014). Catalytic activity of chloro and triflate manganese(II) complexes in epoxidation reactions. Reusable catalytic systems for alkene epoxidation..
Eur. J. Inorg. Chem.. 2014, 2663–2670.
Gennari, M., Gerey B., Hall N., Pécaut J., Collomb M-N., Rouzières M., et al.
(2014). A Bio-Inspired Switch Based on Cobalt(II) Disulfide/Cobalt(III) Thiolate Interconversion..
Angew. Chemie, Int. Ed.. 53, 5318–5321.
Hall, N., Orio M., Jorge-Robin A., Gennaro B., Marchi-Delapierre C., & Duboc C.
(2013). Vanadium Thiolate Complexes for Efficient and Selective Sulfoxidation Catalysis: A Mechanistic Investigation..
Inorg. Chem.. 52, 13424–13431.
Hakouk, K., Oms O., Dolbecq A., Moll H. El, Marrot J., Evain M., et al.
(2013). Sulfonium Polyoxometalates: A New Class of Solid-State Photochromic Hybrid Organic-Inorganic Materials..
Inorg. Chem.. 52, 555–557.
Gennari, M., Gerey B., Hall N., Pécaut J., Vezin H., Collomb M-N., et al.
(2012). Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex - the reactivity toward S-alkylation: an experimental and theoretical study..
Dalt. Trans.. 41, 12586–12594.
Castillo, C. E., Romain S., Retegan M., Leprêtre J-C., Chauvin J., Duboc C., et al.
(2012). Visible-Light-Driven Generation of High-Valent Oxo-Bridged Dinuclear and Tetranuclear Manganese Terpyridine Entities Linked to Photoactive Ruthenium Units of Relevance to Photosystem II..
Eur. J. Inorg. Chem.. 2012, 5485–5499.
Barchasz, C., Molton F., Duboc C., Leprêtre J-C., Patoux S., & Alloin F..
(2012). Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification..
Anal. Chem. (Washington, DC, United States). 84, 3973–3980.
Castillo, C. E., Algarra A. G., M Manez A., Duboc C., & Basallote M. G.
(2012). The Solution Chemistry of Cu2+-tren Complexes Revisited: Exploring the Role of Species That Are Not Trigonal Bipyramidal..
Eur. J. Inorg. Chem.. 2012, 2514–2526.
Orio, M., Jarjayes O., Baptiste B., Philouze C., Duboc C., Mathias J-L., et al.
(2012). Geometric and Electronic Structures of Phenoxyl Radicals Hydrogen Bonded to Neutral and Cationic Partners..
Chem. - A Eur. J.. 18, 5416–5429, S5416/1–S5416/13.
Gennari, M., Pécaut J., Collomb M-N., & Duboc C.
(2012). A copper thiolate centre for electron transfer: mononuclear vs. dinuclear complexes..
Dalt. Trans.. 41, 3130–3133.
Motreff, A., da Costa R. Correa, Allouchi H., Duttine M., Mathonière C., Duboc C., et al.
(2012). A fluorous copper(II)-carboxylate complex which magnetically and reversibly responds to humidity in the solid state..
J. Fluor. Chem.. 134, 49–55.
Roemelt, M., Beckwith M. A., Duboc C., Collomb M-N., Neese F., & DeBeer S..
(2012). Manganese K-Edge X-Ray Absorption Spectroscopy as a Probe of the Metal-Ligand Interactions in Coordination Compounds..
Inorg. Chem.. 51, 680–687.
Trepreau, J., de Rosny E., Duboc C., Sarret G., Petit-Härtlein I., Maillard A. P., et al.
(2011). Spectroscopic Characterization of the Metal-Binding Sites in the Periplasmic Metal-Sensor Domain of CnrX from Cupriavidus metallidurans CH34..
Biochemistry. 50, 9036–9045.
Romain, S., Rich J., Sens C., Stoll T., Benet-Buchholz J., Llobet A., et al.
(2011). Multireversible Redox Processes in Pentanuclear Bis(Triple-Helical) Manganese Complexes Featuring an Oxo-Centered triangular \MnII2MnIII($μ$3-O)\}5+ or \MnIIMnIII2($μ$3-O)\}6+ Core Wrapped by Two \MnII2(bpp)3\}-.}.
Inorg. Chem.. 50, 8427–8436.
Romain, S., Duboc C., Retegan M., Leprêtre J-C., Blackman A., Deronizer A., et al.
(2011). Electrochemical formation of bi- versus tetranuclear $μ$-oxo terpyridine manganese complexes in CH3CN. Influence of the terpyridine substituents..
Inorganica Chim. Acta. 374, 187–196.
Gennari, M., Retegan M., DeBeer S., Pécaut J., Neese F., Collomb M-N., et al.
(2011). Experimental and Computational Investigation of Thiolate Alkylation in NiII and ZnII Complexes: Role of the Metal on the Sulfur Nucleophilicity..
Inorg. Chem.. 50, 10047–10055.
Beckwith, M. A., Roemelt M., Collomb M-N., Duboc C., Weng T-C., Bergmann U., et al.
(2011). Manganese K$\beta$ X-ray Emission Spectroscopy As a Probe of Metal-Ligand Interactions..
Inorg. Chem.. 50, 8397–8409.
Gennari, M., Orio M., Pécaut J., Bothe E., Neese F., Collomb M-N., et al.
(2011). Influence of Mixed Thiolate/Thioether versus Dithiolate Coordination on the Accessibility of the Uncommon +I and +III Oxidation States for the Nickel Ion: An Experimental and Computational Study..
Inorg. Chem.. 50, 3707–3716.
Gennari, M., Pécaut J., DeBeer S., Neese F., Collomb M-N., & Duboc C.
(2011). A Fully Delocalized Mixed-Valence Bis-$μ$(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center..
Angew. Chemie, Int. Ed.. 50, 5662–5666, S5662/1–S5662/16.
Nguyen, V., Tiritiris I., Winter R. F., Sarkar B., Singh P., Duboc C., et al.
(2010). Oxidative perhydroxylation of [closo-B12H12]2- to the stable inorganic cluster redox system [B12(OH)12]2-/·-: experiment and theory..
Chem. - A Eur. J.. 16, 11242–11245, S11242/1–S11242/8.
Duboc, C., Ganyushin D., Sivalingam K., Collomb M-N., & Neese F.
(2010). Systematic Theoretical Study of the Zero-Field Splitting in Coordination Complexes of Mn(III). Density Functional Theory versus Multireference Wave Function Approaches..
J. Phys. Chem. A. 114, 10750–10758.
Compain, J-D., Mialane P., Dolbecq A., Mbomekallé I. Martyr, Marrot J., Sécheresse F., et al.
(2010). Structural, Magnetic, EPR, and Electrochemical Characterizations of a Spin-Frustrated Trinuclear CrIII Polyoxometalate and Study of Its Reactivity with Lanthanum Cations..
Inorg. Chem.. 49, 2851–2858.
Gasnier, A., Barbe J-M., Bucher C., Duboc C., Moutet J-C., Saint-Aman E., et al.
(2010). Soluble Heterometallic Coordination Polymers Based on a Bis-terpyridine-Functionalized Dioxocyclam Ligand..
Inorg. Chem.. 49, 2592–2599.
Motreff, A., da Costa R. Correa, Allouchi H., Duttine M., Mathonière C., Duboc C., et al.
(2009). Dramatic Solid-State Humidity-Induced Modification of the Magnetic Coupling in a Dimeric Fluorous Copper(II)-Carboxylate Complex..
Inorg. Chem.. 48, 5623–5625.
Zális, S., Sarkar B., Duboc C., & Kaim W..
(2009). Evidence for the dimer-of-(mixed-valent dimers) configuration in tetranuclear \($μ$4-TCNX)[Ru(NH3)5]4\}8+.
Monatshefte fuer Chemie. 140, 765–773.
Frantz, S., Sieger M., Hartenbach I., Lissner F., Schleid T., Fiedler J., et al.
(2009). Structure, electrochemistry, spectroscopy, and magnetic resonance, including high-field EPR, of \($μ$-abpy)[Re(CO)3X]2\}o/·-, where abpy = 2,2'-azobispyridine and X = F, Cl, Br, I.}.
J. Organomet. Chem.. 694, 1122–1133.
Romain, S., Baffert C., Duboc C., Leprêtre J-C., Deronizer A., & Collomb M-N.
(2009). Mononuclear MnIII and MnIV Bis-terpyridine Complexes: Electrochemical Formation and Spectroscopic Characterizations..
Inorg. Chem.. 48, 3125–3131.
Romain, S., Duboc C., Neese F., Rivière E., Hanton L. R., Blackman A., et al.
(2009). An unusual stable mononuclear MnIII bis-terpyridine complex exhibiting Jahn-Teller compression: electrochemical synthesis, physical characterisation and theoretical study..
Chem. - A Eur. J.. 15, 980–988.
Duboc, C., & Collomb M-N.
(2009). Multifrequency high-field EPR investigation of a mononuclear manganese(iv) complex..
Chem. Commun. (Cambridge, United Kingdom). 2715–2717.
Das, A. Kumar, Sarkar B., Duboc C., Strobel S., Fiedler J., Zális S., et al.
(2009). An Odd-Electron Complex [Ruk(NOm)(Qn)(terpy)]2+ with Two Prototypical Non-Innocent Ligands..
Angew. Chemie, Int. Ed.. 48, 4242–4245, S4242/1–S4242/6.
Duboc, C., Collomb M-N., & Neese F.
(2009). Understanding the Zero-Field Splitting of Mononuclear Manganese(II) Complexes from Combined EPR Spectroscopy and Quantum Chemistry..
Appl. Magn. Reson.. 37, 229–245.
Baffert, C., Orio M., Pantazis D. A., Duboc C., Blackman A., Blondin G., et al.
(2009). Trinuclear Terpyridine Frustrated Spin System with a MnIV3O4 Core: Synthesis, Physical Characterization, and Quantum Chemical Modeling of Its Magnetic Properties..
Inorg. Chem.. 48, 10281–10288.
Roy, S., Sarkar B., Duboc C., Fiedler J., Sarper O., Lissner F., et al.
(2009). Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3e) or Reduction (2e) to Spectroelectrochemically Characterized Species..
Chem. - A Eur. J.. 15, 6932–6939, S6932/1–S6932/7.
Maity, A. N., Sarkar B., Niemeyer M., Sieger M., Duboc C., Zális S., et al.
(2008). A tetranuclear organorhenium(I) complex of the 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane radical anion, TCNQF4-..
Dalt. Trans.. 5749–5753.
Sarkar, B., Frantz S., Roy S., Sieger M., Duboc C., Denninger G., et al.
(2008). High-frequency EPR and structural data as complementary information on stable radical complexes containing the semi-reduced azo function..
J. Mol. Struct.. 890, 133–138.
Hureau, C., Groni S., Guillot R., Blondin G., Duboc C., & Anxolabehere-Mallart E..
(2008). Syntheses, X-ray Structures, Solid State High-Field Electron Paramagnetic Resonance, and Density-Functional Theory Investigations on Chloro and Aqua MnII Mononuclear Complexes with Amino-Pyridine Pentadentate Ligands..
Inorg. Chem.. 47, 9238–9247.
Duboc, C., Collomb M-N., Pécaut J., Deronizer A., & Neese F.
(2008). Definition of magneto-structural correlations for the MnII ion..
Chem. - A Eur. J.. 14, 6498–6509.
Roy, S., Sieger M., Singh P., Niemeyer M., Fiedler J., Duboc C., et al.
(2008). A radical-bridged bis(ferrocenylcopper(I)) complex: Structural identity, multifrequency EPR, and spectroelectrochemistry..
Inorganica Chim. Acta. 361, 1699–1704.
Zein, S., Duboc C., Lubitz W., & Neese F.
(2008). A Systematic Density Functional Study of the Zero-Field Splitting in Mn(II) Coordination Compounds..
Inorg. Chem.. 47, 134–142.
Pordea, A., Creus M., Panek J., Duboc C., Mathis D., Novic M., et al.
(2008). Artificial Metalloenzyme for Enantioselective Sulfoxidation Based on Vanadyl-Loaded Streptavidin..
J. Am. Chem. Soc.. 130, 8085–8088.
Singh, P., Fiedler J., Zális S., Duboc C., Niemeyer M., Lissner F., et al.
(2007). Spectroelectrochemistry and DFT Analysis of a New \RuNO\}n Redox System with Multifrequency EPR Suggesting Conformational Isomerism in the \RuNO\}7 State.}.
Inorg. Chem.. 46, 9254–9261.
Pichon, C., Mialane P., Rivière E., Blain G., Dolbecq A., Marrot J., et al.
(2007). The Highest D Value for a MnII Ion: Investigation of a Manganese(II) Polyoxometalate Complex by High-Field Electron Paramagnetic Resonance..
Inorg. Chem.. 46, 7710–7712.
Maity, A. N., Schwederski B., Sarkar B., Zális S., Fiedler J., Kar S., et al.
(2007). Tetranuclear Complexes of [Fe(CO)2(C5H5)]+ with TCNX Ligands (TCNX = TCNE, TCNQ, TCNB): Intramolecular Electron Transfer Alternatives in Compounds ($μ$4-TCNX)[MLn]4..
Inorg. Chem.. 46, 7312–7320.
Duboc, C., Phoeung T., Zein S., Pécaut J., Collomb M-N., & Neese F.
(2007). Origin of the Zero-Field Splitting in Mononuclear Octahedral Dihalide MnII Complexes: An Investigation by Multifrequency High-Field Electron Paramagnetic Resonance and Density Functional Theory..
Inorg. Chem.. 46, 4905–4916.
Koval, I. A., Akhideno H., Tanase S., Belle C., Duboc C., Saint-Aman E., et al.
(2007). Changes in magnetic properties from solid state to solution in a trinuclear linear copper(II) complex..
New J. Chem.. 31, 512–518.
Collomb, M-N., Mantel C., Romain S., Duboc C., Leprêtre J-C., Pécaut J., et al.
(2007). Redox-induced $μ$-acetato and $μ$-oxo core interconversions in dinuclear manganese tris(2-pyridylmethyl)amine (tpa) complexes: isolation and characterization of [Mn2III($μ$-O)($μ$-O2CCH3)(tpa)2]3+..
Eur. J. Inorg. Chem.. 3179–3187.
Duboc, C., Phoeung T., Damien Jouvenot, Blackman A., McClintock L. F., Pécaut J., et al.
(2007). High-field EPR investigation of a series of mononuclear Mn(II) complexes doped into Zn(II) hosts..
Polyhedron. 26, 5243–5249.
Rammal, W., Belle C., Béguin C., Duboc C., Philouze C., Pierre J-L., et al.
(2006). Multifrequency EPR and Redox Reactivity Investigations of a Bis(μ-thiolato)-dicopper(II,II) Complex..
Inorg. Chem.. 45, 10355–10362.
Lisnard, L., Dolbecq A., Mialane P., Marrot J., Rivière E., Borshch S. A., et al.
(2006). Synthesis and characterizations of cyclic octanuclear mixed-valence vanadium(IV,V) clusters with polyoxometalate counterions..
Dalt. Trans.. 5141–5148.
Mialane, P., Duboc C., Marrot J., Rivière E., Dolbecq A., & Secheresse F..
(2006). Structural and magnetic properties of MnIII and CuII tetranuclear azido polyoxometalate complexes: multifrequency high-field EPR spectroscopy of Cu4 clusters with S = 1 and S = 2 ground states..
Chem. - A Eur. J.. 12, 1950–1959.
Heilmann, M., Frantz S., Kaim W., Fiedler J., & Duboc C.
(2006). {{Mixed-valent and radical states of complexes [(bpy)2M($μ$-abpy)M'(bpy)2]n+, M,M' = Ru or Os.
Inorganica Chim. Acta. 359, 821–829.
Duboc, C., Astier-Perret V., Chen H., Pécaut J., Crabtree R. H., Brudvig G. W., et al.
(2006). A multifrequency high-field EPR (9-285GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes..
Inorganica Chim. Acta. 359, 1541–1548.
Mantel, C., Chen H., Crabtree R. H., Brudvig G. W., Pécaut J., Collomb M-N., et al.
(2005). High-spin chloro mononuclear MnIII complexes: a multifrequency high-field EPR study..
ChemPhysChem. 6, 541–546.
Thomas, F., Jarjayes O., Jamet H., Hamman S., Saint-Aman E., Duboc C., et al.
(2004). How single and bifurcated hydrogen bonds influence proton-migration rate constants, redox, and electronic properties of phenoxyl radicals..
Angew. Chemie, Int. Ed.. 43, 594–597.
Mantel, C., Philouze C., Collomb M-N., & Duboc C.
(2004). Investigation of a neat versus magnetically diluted powdered mononuclear MnII complex by high-field and high-frequency EPR spectroscopy..
Eur. J. Inorg. Chem.. 3880–3886.
Mantel, C., Baffert C., Romero I., Deronzier A., Pécaut J., Collomb M-N., et al.
(2004). Structural Characterization and Electronic Properties Determination by High-Field and High-Frequency EPR of a Series of Five-Coordinated Mn(II) Complexes..
Inorg. Chem.. 43, 6455–6463.
Mantel, C., Hassan A. K., Pécaut J., Deronzier A., Collomb M-N., & Duboc C.
(2003). A High-Frequency and High-Field EPR Study of New Azide and Fluoride Mononuclear Mn(III) Complexes..
J. Am. Chem. Soc.. 125, 12337–12344.
Gorgy, K., Collomb M-N., Leprêtre J-C., Deronzier A., Duboc C., Ménage S., et al.
(2001). An easy electrochemical procedure for tailoring thin films containing the [Fe(bpy)2(CH3CN)2]2+ and/or [Fe(bpy)3]2+-like cores (bpy=2,2'-bipyridine). Application to the design of a modified electrode with a supramolecular structure..
Electrochem. commun.. 3, 686–691.
Limburg, J., Vrettos J. S., Crabtree R. H., Brudvig G. W., de Paula J. C., Hassan A., et al.
(2001). High-Frequency EPR Study of a New Mononuclear Manganese(III) Complex: [(terpy)Mn(N3)3] (terpy = 2,2':6',2''-Terpyridine)..
Inorg. Chem.. 40, 1698–1703.
I received my PhD from the University of Grenoble in 1998 under the supervision of Professor Marc Fontecave and Doctor Stephane Menage. Following a postdoctoral position at the University of Minnesota, with Professor William Tolman, I joined the High Magnetic Field Laboratory at Grenoble in 2000 and the Department of Molecular Chemistry at Grenoble in 2007, where I am now CNRS senior researcher. My current research interests are on (i) bio-inspired complexes containing metal-sulfur bond(s) to develop catalysts for the activation of small molecules via multi-redox processes and (ii) the elucidation of the magnetic properties of transition metal ion complexes based on a combined experimental and theoretical approach.
Awards & Distinctions
2022 Senior Researcher Award of the French Chemical Society, Division of Coordination Chemistry
2020 Associate Editor @ JACS Au
2016 Nominated @ AcademiaNet: The portal to excellent women academics
2007 CNRS Bronze Medal
2007 Young Researcher Award of the French Chemical Society, Division of Physical Chemistry
Awards & Distinctions
2022 Senior Researcher Award of the French Chemical Society, Division of Coordination Chemistry
2020 Associate Editor @ JACS Au
2016 Nominated @ AcademiaNet: The portal to excellent women academics
2007 CNRS Bronze Medal
2007 Young Researcher Award of the French Chemical Society, Division of Physical Chemistry
CONTACT
Bâtiment : Chimie C
Bureau : bureau 125
0476748877
TRAVAUX MAJEURS
- A Non-Heme Diiron Complex for (Electro)catalytic Reduction of Dioxygen: Tuning the Selectivity through Electron Delivery
- Bioinspired Molecular Electrocatalysts for H2 Production: Chemical Strategies
- Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase.
- Repurposing a Bio-Inspired NiFe Hydrogenase Model for CO2 Reduction with Selective Production of Methane as the Unique C-Based Product