Site du DCM - Université Grenoble Alpes

SYLVIE CHARDON

Directrice de recherche (CNRS)

Affiliation

Centre national de la recherche scientifique

Équipe de recherche

DCM-EMPRE

Domaines de recherche

Molecular electrochemistry-Coordination chemistry-Modified electrochemical interfaces-Electro and photo redox molecular catalysis-Transformation and valorization of CO2

Disciplines scientifiques

Chimie organique, minérale, industrielle

Habilitation à diriger des recherches

HDR in Chemistry

ORCID Sylvie Chardon

Guyot, M., Lalloz M-N., Aguirre-Araque J. S., Rogez G., Costentin C., & Chardon S. (2022). Rhenium Carbonyl Molecular Catalysts for CO2 Electroreduction: Effects on Catalysis of Bipyridine Substituents Mimicking Anchorage Functions to Modify Electrodes. Inorganic Chemistry. 61, 16072-16080.

Tarhini, A., Aguirre-Araque J., Guyot M., Costentin C., Rogez G., Chardon S., et al. (2022). Behavior of iron tetraphenylsulfonato porphyrin intercalated into LDH and LSH as materials for electrocatalytic applications. Electrocatalysis.

Deeba, R., Molton F., Chardon S., & Costentin C. (2021). Effective Homogeneous Catalysis of Electrochemical Reduction of Nitrous Oxide to Dinitrogen at Rhenium Carbonyl Catalysts. ACS Catalysis. 11, 6099-6103.

Deeba, R., Chardon S., & Costentin C. (2021). Homogeneous molecular catalysis of the electrochemical reduction of N2O to N2: redox vs. chemical catalysis. Chem. Sci.. 12, 12726-12732.

Deeba, R., Chardon S., & Costentin C. (2021). Molecular Catalysis of Electrochemical Reactions: Competition between Reduction of the Substrate and Deactivation of the Catalyst by a Cosubstrate Application to N2O Reduction. ChemElectroChem. 8, 3740-3744.

Coin, G., Patra R., Clemancey M., Dubourdeaux P., Pécaut J., Lebrun C., et al. (2019). Fe-Based Complexes as Styrene Aziridination Catalysts: Ligand Substitution Tunes Catalyst Activity. ChemCatChem. 11, 5296-5299.

Le-Quang, L., Stanbury M., Chardon S., Mouesca J-M., Maurel V., & Chauvin J. (2019). Immobilization of Mn(i) and Ru(ii) polypyridyl complexes on TiO2 nanoparticles for selective photoreduction of CO2 to formic acid. Chem. Commun.. 55, 13598-13601.

Stanbury, M., Compain J-D., & Chardon S. (2018). Electro and photoreduction of CO2 driven by manganese-carbonyl molecular catalysts.. Coord. Chem. Rev.. 361, 120–137.

Oyarzun, D. P., Chardon S., Perez O. E. Linarez, Teijelo M. Lopez, Zuniga C., Zarate X., et al. (2018). Comparative study of the anchorage and the catalytic properties of nanoporous TiO2 films modified with ruthenium (II) and rhenium (I) carbonyl complexes.. Chem. Phys. Lett.. 694, 40–47.

Stanbury, M., Compain J-D., Trejo M., Smith P., Gouré E., & Chardon S. (2017). Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH.. Electrochim. Acta. 240, 288–299.

Castillo, C. E., Armstrong J., Laurila E., Oresmaa L., Haukka M., Chauvin J., et al. (2016). Electro- and Photo-driven Reduction of CO2 by a trans-(Cl)-[Os(diimine)(CO)2Cl2] Precursor Catalyst: Influence of the Diimine Substituent and Activation Mode on CO/HCOO- Selectivity.. ChemCatChem. 8, 2667–2677.

Bitar, Z., Fecant A., Trela-Baudot E., Chardon S., & Pasquier D.. (2016). Electrocatalytic reduction of carbon dioxide on indium coated gas diffusion electrodes-Comparison with indium foil.. Appl. Catal. B Environ.. 189, 172–180.

Bitard, Z., Pasquier D., Fecant A., Chardon S., & Deronzier A.. (2016). Method of preparation of an activated layer containing polymerized metal complexes, and use as a cathode for carbon dioxide electroreduction..

Compain, J-D., Stanbury M., Trejo M., & Chardon S. (2015). Carbonyl-Terpyridyl-Manganese Complexes: Syntheses, Crystal Structures, and Photo-Activated Carbon Monoxide Release Properties.. Eur. J. Inorg. Chem.. 2015, 5757–5766.

Torralba-Penalver, E., Luo Y., Compain J-D., Chardon S., & Fabre B.. (2015). Selective Catalytic Electroreduction of CO2 at Silicon Nanowires (SiNWs) Photocathodes Using Non-Noble Metal-Based Manganese Carbonyl Bipyridyl Molecular Catalysts in Solution and Grafted onto SiNWs.. ACS Catal.. 5, 6138–6147.

Pasquier, D., Fecant A., Bitard Z., Chardon S., & Deronzier A.. (2014). Active layer made of metal complexes on a porous conductive substrate with large specific surface area, manufacturing method and use as cathode for electroreduction of carbon dioxide..

Fischer, B., Pasquier D., Chardon S., & Deronzier A.. (2014). Method of producing formic acid by electrocatalytic reduction in the gaseous phase of the CO2 using a gas-diffusion cathode..

Pasquier, D., Fecant A., Bitar Z., Chardon S., & Deronzier A.. (2014). Active layer made of metal complexes on a porous conductive substrate with large specific surface area, manufacturing method and use as cathode for electroreduction of carbon dioxide..

Fischer, B., Pasquier D., Chardon S., & Deronzier A.. (2014). Formic acid manufacturing process via electrocatalytic reduction of CO2 in the gas phase using gas-diffusion cathode..

Compain, J-D., Bourrez M., Haukka M., Deronizer A., & Chardon S. (2014). Manganese carbonyl terpyridyl complexes: their synthesis, characterization and potential application as CO-release molecules.. Chem. Commun. (Cambridge, United Kingdom). 50, 2539–2542.

Mechouet, M., Perruchot C., Maurel F., Aeiyach S., Bucher C., Chardon S., et al. (2012). Intervalence Charge Transfer in Mixed Valence Compound Modified by the Formation of a Supramolecular Complex.. J. Phys. Chem. A. 116, 970–978.

Lokesh, K. Sannegowda, Chardon S., Lafolet F., Traore Y., Gondran C., Guionneau P., et al. (2012). One-Step vs Stepwise Immobilization of 1-D Coordination-Based Rh-Rh Molecular Wires on Gold Surfaces.. Langmuir. 28, 11779–11789.

Bourrez, M., Molton F., Chardon S., & Deronizer A. (2011). [Mn(bipyridyl)CO3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction.. Angew. Chemie, Int. Ed.. 50, 9903–9906, S9903/1–S9903/9.

Chauvin, J., Lafolet F., Chardon S., Deronizer A., Jakonen M., & Haukka M.. (2011). Towards New Molecular Photocatalysts for CO2 Reduction: Photo-Induced Electron Transfer versus CO Dissociation within [Os(NN)(CO)2Cl2] Complexes.. Chem. - A Eur. J.. 17, 4313–4322.

Gerbaud, G., Mouesca J-M., Hediger S., Chardon S., Lafolet F., Deronizer A., et al. (2010). Structural characterization of metal-metal bonded polymer [Ru(L)(CO)2]n (L = 2,2'-bipyridine) in the solid state using high-resolution NMR and DFT chemical shift calculations.. Phys. Chem. Chem. Phys.. 12, 15428–15435.

Cwikowska, M., Pruchnik F. P., Pavlyuk O., Lafolet F., Chardon S., & Deronizer A. (2010). Soluble [Rh2(μ-OOCCH3)2(dbbpy)2][BF4]n molecular wire and [Rh2(μ-OOCCH3)2(dbbpy)2L2]2+ complexes; dbbpy = 4,4′-di-tert-butyl-2,2′-bipyridine: Synthesis and physicochemical characterization. Polyhedron. 29, 3059–3065.

Ramiz, M. M., Hassan K. M., Khudaish E. A., Deronizer A., Chardon S., & M Azzem A. (2010). Anodic polymerization of 1-amino-2-methyl-9, 10-anthraquinone in mixed solvent.. J. Electroanal. Chem.. 647, 35–42.

Hartl, F., Renfrew A. K., Lafolet F., Mahabiersing T., Calhorda M. Jose, Chardon S., et al. (2009). Soluble Redox-Active Polymetallic Chains [Ru0(CO)(L)(bpy)m]n (bpy = 2,2′-bipyridine, L = PrCN, Cl−; m = 0, −1): Electrosynthesis and Characterization. Inorg. Chem.. 48, 8233–8244.

Rak, M., Pruchnik F. P., Ciunik L. Z., Lafolet F., Chardon S., & Deronizer A. (2009). Synthesis and structural and physicochemical characterization of \[Rh2($μ$-OOCCH3)2(dmbpy)2][BF4]\}n molecular wire.}. Eur. J. Inorg. Chem.. 111–118.

Lafolet, F., Chardon S., Duboc C., Deronizer A., Pruchnik F. P., & Rak M.. (2008). Electrochemical fabrication and characterization of thin films of redox-active molecular wires based on extended Rh-Rh bonded chains.. Dalt. Trans.. 2149–2156.

Avenier, F., Gouré E., Dubourdeaux P., Seneque O., Oddou J-L., Pécaut J., et al. (2008). Multiple aromatic amination mediated by a diiron complex.. Angew. Chemie, Int. Ed.. 47, 715–717.

Chardon, S., Renfrew A., Lafolet F., Deronizer A., Jakonen M., Laurila E., et al. (2008). An easy electrochemical and chemical synthesis of [Ru(bpy)(CH3CN)2Cl2]: a synthon for heteroleptic tris(diimine) Ru(II) complexes.. Dalt. Trans.. 5891–5896.

De Pascali, S. A., Migoni D., Papadia P., Romano A., Marsigliante S., Pellissier A., et al. (2008). New mononuclear and homodinuclear Pt(II) complexes with heterocyclic nitrogen chelates: Synthesis, characterization, intercalating ability and in vitro cytotoxic activity evaluation.. Dalt. Trans.. 5911–5921.

Jakonen, M., Hirva P., Haukka M., Chardon S., Lafolet F., Chauvin J., et al. (2007). An alternative synthesis method for [Os(NN)(CO)2X2] complexes (NN = 2,2'-bipyridine, 4,4'-dimethyl-2,2'-bipyridine; X = Cl, Br, I). Electrochemical and photochemical properties and behavior.. Dalt. Trans.. 3314–3324.

Chardon, S., Pellissier A., Cripps G., & Deronizer A. (2006). Electrochemical behavior of binuclear [Ru(L)(CO)2(CH3CN)]22+ complexes (L = 2,2'-bipyridine substituted by pyrrole groups). Their reductive and oxidative electropolymerization.. J. Electroanal. Chem.. 597, 28–38.

Dubois, L., Xiang D-F., Tan X-S., Pécaut J., Jones P., Baudron S., et al. (2003). Binuclear Manganese Compounds of Potential Biological Significance. 1. Syntheses and Structural, Magnetic, and Electrochemical Properties of Dimanganese(II) and -(II,III) Complexes of a Bridging Unsymmetrical Phenolate Ligand.. Inorg. Chem.. 42, 750–760.

Orillon, M., Chardon S., Collomb M-N., Deronzier A., Ziessel R., & Zsoldos D.. (1997). Carbon dioxide-reducing cathode..

Chardon, S., Collomb M-N., Deronzier A., Ziessel R., & Zsoldos D.. (1994). Formation of Polymeric [\Ru0(bpy)(CO)2\}n] Films by Electrochemical Reduction of [Ru(bpy)2(CO)2](PF6)2: Its Implication in CO2 Electrocatalytic Reduction.}. Inorg. Chem.. 33, 4410–4412.

CONTACT

Bâtiment : Chimie C

Bureau : 315

0476187815

Sylvie.Chardon@univ-grenoble-alpes.fr

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