OLIVIER JARJAYES
Maître de conférences
Affiliation
Université Grenoble Alpes
Équipe de recherche
DCM-CIRE
Domaines de recherche
Ligand design and synthesis, Coordination chemistry. Metal-radical chemistry. Salen complexes.
Disciplines scientifiques
Chimie organique, minérale, industrielle
Habilitation à diriger des recherches
Control of the oxidation site of Ni(II) salen complexes
Thèse
Synthesis and characterisation of electronic conducting polymers including nano sized magnetic particles
sous la direction de Dr G. Bidan
sous la direction de Dr G. Bidan
Enseignement
- General Chemistry and Inorganic Chemistry : Semesters 1 and 2
- Experimental Inorganic Chemistry : Semester 3
- Inorganic Chemistry : Semester 5
- Mineral Chemistry : 6
- Bioinorganic Chemistry : Semester 8
- Experimental Inorganic Chemistry : Semester 3
- Inorganic Chemistry : Semester 5
- Mineral Chemistry : 6
- Bioinorganic Chemistry : Semester 8
Kunert, R.., Philouze C., Berthiol F.., Jarjayes O., Storr T.., & Thomas F.
(2020). Distorted copper(ii) radicals with sterically hindered salens: electronic structure and aerobic oxidation of alcohols.
Dalton Trans.. 49, 12990-13002.
Kanso, H., Clarke R. M., Kochem A., Arora H., Philouze C., Jarjayes O., et al.
(2020). Effect of Distortions on the Geometric and Electronic Structures of One-Electron Oxidized Vanadium(IV), Copper(II), and Cobalt(II)/(III) Salen Complexes.
Inorganic Chemistry. 59, 5133-5148.
Mouchel dit Leguerrier, D., Barré R., Bryden M.., Imbert D.., Philouze C., Jarjayes O., et al.
(2020). Structural and spectroscopic investigations of nine-coordinate redox active lanthanide complexes with a pincer O,N,O ligand.
Dalton Trans.. 49, 8238-8246.
Kunert, R., Philouze C., Jarjayes O., & Thomas F.
(2019). Stable M(II)-Radicals and Nickel(III) Complexes of a Bis(phenol) N-Heterocyclic Carbene Chelated to Group 10 Metal Ions.
Inorganic Chemistry. 58, 8030-8044.
Molloy, J. K., Philouze C., Fedele L., Imbert D., Jarjayes O., & Thomas F.
(2018). Seven-coordinate lanthanide complexes with a tripodal redox active ligand: structural, electrochemical and spectroscopic investigations..
Dalton transactions (Cambridge, England : 2003). 47, 10742–10751.
Molloy, J. K., Fedele L., Jarjayes O., Philouze C., Imbert D., & Thomas F.
(2018). Structural and spectroscopic investigations of redox active seven coordinate luminescent lanthanide complexes.
Inorganica Chimica Acta. 483, 609 - 617.
Gandara, C., Philouze C., Jarjayes O., & Thomas F.
(2018). Coordination chemistry of a redox non-innocent NHC bis(phenolate) pincer ligand with nickel(II).
Inorganica Chimica Acta. 482, 561 - 566.
Kochem, A., Molloy J. K., Gellon G., Leconte N., Philouze C., Berthiol F., et al.
(2017). A Structurally Characterized CuIII Complex Supported by a Bis(anilido) Ligand and Its Oxidative Catalytic Activity..
Chem. Eur. J.. 23, 13929–13940.
Bonnat, L., Bar L., Gennaro B., Bonnet H., Jarjayes O., Thomas F., et al.
(2017). Template-mediated stabilization of a DNA G-quadruplex formed in the HIV-1 promoter and comparative binding studies..
Chem. - A Eur. J.. 23, 5602–5613.
Molloy, J. K., Jarjayes O., Philouze C., Fedele L., Imbert D., & Thomas F.
(2017). A redox active switch for lanthanide luminescence in phenolate complexes..
Chem. Commun. (Cambridge, United Kingdom). 53, 605–608.
Lecarme, L., Prado E., De Rache A., Nicolau-Travers M-L., Gellon G., Dejeu J., et al.
(2016). Efficient Inhibition of Telomerase by Nickel-Salophen Complexes..
ChemMedChem. 11, 1133–1136.
Bonnat, L., Dejeu J., Bonnet H., Gennaro B., Jarjayes O., Thomas F., et al.
(2016). Templated Formation of Discrete RNA and DNA:RNA Hybrid G-Quadruplexes and Their Interactions with Targeting Ligands..
Chem. - A Eur. J.. 22, 3139–3147.
Lecarme, L., Chiang L., Moutet J., Leconte N., Philouze C., Jarjayes O., et al.
(2016). The structure of a one-electron oxidized Mn(iii)-bis(phenolate)dipyrrin radical complex and oxidation catalysis control via ligand-centered redox activity.
Dalton Trans.. 45, 16325-16334.
Kochem, A., Gellon G., Jarjayes O., Philouze C., Du Moulinet D'Hardemare A., van Gastel M., et al.
(2015). Nickel(II) radical complexes of thiosemicarbazone ligands appended by salicylidene, aminophenol and aminothiophenol moieties..
Dalt. Trans.. 44, 12743–12756.
Lecarme, L., Prado E., De Rache A., Nicolau-Travers M-L., Bonnet R., Van der Heyden A., et al.
(2014). Interaction of Polycationic Ni(II)-Salophen Complexes with G-Quadruplex DNA..
Inorg. Chem.. 53, 12519–12531.
Kochem, A., Gellon G., Jarjayes O., Philouze C., Leconte N., van Gastel M., et al.
(2014). A singlet ground state for a cobalt(II)-anilinosalen radical complex..
Chem. Commun. (Cambridge, United Kingdom). 50, 4924–4926.
Kochem, A., Gellon G., Leconte N., Baptiste B., Philouze C., Jarjayes O., et al.
(2013). Stable Anilinyl Radicals Coordinated to Nickel: X-ray Crystal Structure and Characterization..
Chem. - A Eur. J.. 19, 16707–16721.
Kochem, A., Jarjayes O., Baptiste B., Philouze C., Vezin H., Tsukidate K., et al.
(2012). One-Electron Oxidized Copper(II) Salophen Complexes: Phenoxyl- Versus Diiminobenzene Radical Species..
Chem. - A Eur. J.. 18, 1068–1072, S1068/1–S1068/20.
Kochem, A., Kanso H., Baptiste B., Arora H., Philouze C., Jarjayes O., et al.
(2012). Ligand Contributions to the Electronic Structures of the Oxidized Cobalt(II) salen Complexes..
Inorg. Chem.. 51, 10557–10571.
Kochem, A., Chiang L., Baptiste B., Philouze C., Leconte N., Jarjayes O., et al.
(2012). Ligand-Centered Redox Activity in Cobalt(II) and Nickel(II) Bis(phenolate)-Dipyrrin Complexes..
Chem. - A Eur. J.. 18, 14590–14593, S14590/1–S14590/51.
Chiang, L., Kochem A., Jarjayes O., Dunn T. J., Vezin H., Sakaguchi M., et al.
(2012). Radical Localization in a Series of Symmetric NiII Complexes with Oxidized Salen Ligands..
Chem. - A Eur. J.. 18, 14117–14127, S14117/1–S14117/43.
Orio, M., Jarjayes O., Baptiste B., Philouze C., Duboc C., Mathias J-L., et al.
(2012). Geometric and Electronic Structures of Phenoxyl Radicals Hydrogen Bonded to Neutral and Cationic Partners..
Chem. - A Eur. J.. 18, 5416–5429, S5416/1–S5416/13.
Jarjayes, O., Lavergne T., & Thomas F.
(2011). Interaction of Metal Complexes with G-Quadruplexes.
{Encyclopedia of Inorganic and Bioinorganic Chemistry}.
Arora, H., Philouze C., Jarjayes O., & Thomas F.
(2010). CoII, NiII, CuII and ZnII complexes of a bipyridine bis-phenol conjugate: generation and properties of coordinated radical species..
Dalt. Trans.. 39, 10088–10098.
Kochem, A., Orio M., Jarjayes O., Neese F., & Thomas F.
(2010). Unsymmetrical one-electron oxidized Ni(II)-bis(salicylidene) complexes: a protonation-induced shift of the oxidation site..
Chem. Commun. (Cambridge, United Kingdom). 46, 6765–6767.
Thomas, F., Arora H., Philouze C., & Jarjayes O.
(2010). CoIII and CuII complexes of reduced Schiff bases: Generation of phenoxyl radical species..
Inorganica Chim. Acta. 363, 3122–3130.
Orio, M., Jarjayes O., Kanso H., Philouze C., Neese F., & Thomas F.
(2010). X-Ray Structures of Copper(II) and Nickel(II) Radical Salen Complexes: The Preference of Galactose Oxidase for Copper(II)..
Angew. Chemie, Int. Ed.. 49, 4989–4992, S4989/1–S4989/20.
Orio, M., Philouze C., Jarjayes O., Neese F., & Thomas F.
(2010). Spin Interaction in Octahedral Zinc Complexes of Mono- and Diradical Schiff and Mannich Bases..
Inorg. Chem.. 49, 646–658.
Rotthaus, O., Labet V., Philouze C., Jarjayes O., & Thomas F.
(2008). Pseudo-octahedral Schiff base nickel(II) complexes: does single oxidation always lead to the nickel(III) valence tautomer?..
Eur. J. Inorg. Chem.. 4215–4224.
Rotthaus, O., Jarjayes O., Perez del Valle C., Philouze C., & Thomas F.
(2007). A versatile electronic hole in one-electron oxidized NiII bis-salicylidene phenylenediamine complexes..
Chem. Commun. (Cambridge, United Kingdom). 4462–4464.
Rotthaus, O., Jarjayes O., Thomas F., Philouze C., Saint-Aman E., & Pierre J-L..
(2007). Up to four phenoxyl radicals coordinated to two metal ions in copper and zinc complexes?..
Dalt. Trans.. 889–895.
Rotthaus, O., Thomas F., Jarjayes O., Philouze C., Saint-Aman E., & Pierre J-L..
(2006). Valence tautomerism in octahedral and square-planar phenoxyl-nickel(II) complexes: are imino nitrogen atoms good friends?..
Chem. - A Eur. J.. 12, 6953–6962.
Rotthaus, O., Jarjayes O., Thomas F., Philouze C., Perez del Valle C., Saint-Aman E., et al.
(2006). Fine tuning of the oxidation locus, and electron transfer, in nickel complexes of pro-radical ligands..
Chem. - A Eur. J.. 12, 2293–2302.
Thomas, F., Jarjayes O., Jamet H., Hamman S., Saint-Aman E., Duboc C., et al.
(2004). How single and bifurcated hydrogen bonds influence proton-migration rate constants, redox, and electronic properties of phenoxyl radicals..
Angew. Chemie, Int. Ed.. 43, 594–597.
Dr Olivier Jarjayes is an assistant professor at the Grenoble - Alpes University. In 1994, he obtained his PhD in chemistry under the supervision of Dr. G. Bidan (CEA, Laboratoire d'Electrochimie Moléculaire). His PhD consisted in the synthesis of polypyrrole films including coated nano-particules of iron oxide. He did his post-doc in the University J. Fourier at Grenoble with Prof. C. Béguin where he worked on the multinuclear NMR characterization of Ga(III) complexes (iron siderophore mimics).
In 1996 he was appointed assistant professor at Université Joseph Fourier where he started working in the field of group 13 metal radiopharmaceuticals. Now, he conducts his research in the Department of Molecular Chemistry and more specifically in the "Redox-Inorganic Chemistry" group.
His research interests deal with the design and synthesis of redox non innocent ligands mainely derived from the salen backbone and their corresponding metal complexes (Ni(II), Cu(II), Co(II) and Co(III)).
In 1996 he was appointed assistant professor at Université Joseph Fourier where he started working in the field of group 13 metal radiopharmaceuticals. Now, he conducts his research in the Department of Molecular Chemistry and more specifically in the "Redox-Inorganic Chemistry" group.
His research interests deal with the design and synthesis of redox non innocent ligands mainely derived from the salen backbone and their corresponding metal complexes (Ni(II), Cu(II), Co(II) and Co(III)).
