Site du DCM - Université Grenoble Alpes

MARIE-NOELLE COLLOMB

Directrice de recherche (CNRS)

Affiliation

Centre national de la recherche scientifique

Équipe de recherche

DCM-EMPRE

Domaines de recherche

electrochemistry, coordination chemistry, electro- and photocatalysis. Current research interests include the development of molecular and hybrid systems for photocatalytic hydrogen production, nanostructured hydrid (photo)electrode materials for (photo)electrocatalytic water oxidation and reduction, as well as the design of new molecular water reduction catalysts and photosensitizers.

Disciplines scientifiques

Chimie théorique, physique, analytique

Habilitation à diriger des recherches

2002

Thèse

Propriétés électrochimiques et photochimiques de complexes mono(2,2’-bipyridine) carbonyle de ruthénium(II). Applications à la réduction électrocatalytique du CO2 et à la photoimagerie
sous la direction de Alain Deronzier
from 01/10/1990 to 30/09/1993

Responsabilités

Leader of the group “Artificial Photosynthesis and Energy Vectors (PhotoART)” in the Chimie Inorganique Rédox laboratory (CIRE).
ORCID ID: 0000-0002-6641-771X
Scopus Author ID : 7004135795
Research Gate: https://www.researchgate.net/profile/Marie-Noelle_Collomb

Camara, F., Gavaggio T., Dautreppe B., Chauvin J., Pécaut J., Aldakov D., et al. (2022). Electrochemical Properties of a Rhodium(III) Mono-Terpyridyl Complex and Use as a Catalyst for Light-Driven Hydrogen Evolution in Water. Molecules. 27,

Costentin, C., Camara F., Fortage J., & Collomb M-N. (2022). Photoinduced Catalysis of Redox Reactions. Turnover Numbers, Turnover Frequency, and Limiting Processes: Kinetic Analysis and Application to Light-Driven Hydrogen Production. ACS Catalysis. 12, 6246-6254.

Gouré, E., Gerey B., Astudillo C. N., Pécaut J., Sirach S., Molton F., et al. (2021). Self-Assembled Heterometallic Complexes by Incorporation of Calcium or Strontium Ion into a Manganese(II) 12-Metallacrown-3 Framework Supported by a Tripodal Ligand with Pyridine-Carboxylate Motifs: Stability in Their Manganese(III) Oxidized Form. Inorganic Chemistry. 60, 7922-7936.

Morales, D. V., Astudillo C. N., Anastasoaie V., Dautreppe B., Urbano B. F., Rivas B. L., et al. (2021). A cobalt oxide–polypyrrole nanocomposite as an efficient and stable electrode material for electrocatalytic water oxidation. Sustainable Energy & Fuels. 5(18),

Gouré, E., Gerey B., Pécaut J., Thomas F., Fortage J., & Collomb M-N. (2021). Multireversible Redox Processes in a Self-Assembled Nickel Pentanuclear Bis(Triple-stranded Helicate): Structural and Spectroscopic Characterizations in the NiII5 and NiINiII4 Redox States. ChemElectroChem. 8, 2912-2920.

Collomb, M-N., Morales D. V., Astudillo C. N., Dautreppe B., & Fortage J. (2020). Hybrid photoanodes for water oxidation combining a molecular photosensitizer with a metal oxide oxygen-evolving catalyst. Sustainable Energy Fuels. 4, 31-49.

Gouré, E., Gerey B., Molton F., Pécaut J., Clérac R., Thomas F., et al. (2020). Seven Reversible Redox Processes in a Self-Assembled Cobalt Pentanuclear Bis(triple-stranded helicate): Structural, Spectroscopic, and Magnetic Characterizations in the CoICoII4, CoII5, and CoII3CoIII2 Redox States. Inorganic Chemistry. 59, 9196-9205.

Cobo, S., Khettabi A., Grempka A., Lafolet F., Chatir E., Leconte N., et al. (2020). Catalytic light-triggered reduction promoted by a dithienylethene derivative. Chemistry – A European Journal. 26,

Costentin, C., Fortage J., & Collomb M-N. (2020). Electrophotocatalysis: Cyclic Voltammetry as an Analytical Tool. The Journal of Physical Chemistry Letters. 11, 6097-6104.

Gueret, R., Castillo C. E., Rebarz M., Thomas F., Sliwa M., Chauvin J., et al. (2019). Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species. Inorganic Chemistry. 58, 9043-9056.

Castillo, C. E., Stoll T., Sandroni M., Gueret R., Fortage J., Kayanuma M., et al. (2018). Electrochemical Generation and Spectroscopic Characterization of the Key Rhodium(III) Hydride Intermediates of Rhodium Poly(bipyridyl) H2-Evolving Catalysts. Inorganic Chemistry. 57, 11225-11239.

Sandroni, M., Gueret R., Wegner K. D., Reiss P., Fortage J., Aldakov D., et al. (2018). Cadmium-free CuInS2/ZnS quantum dots as efficient and robust photosensitizers in combination with a molecular catalyst for visible light-driven H2 production in water. Energy Environ. Sci..

Morales, D. V., Astudillo C. N., Lattach Y., Urbano B. F., Pereira E., Rivas B. L., et al. (2018). Nickel oxide-polypyrrole nanocomposite electrode materials for electrocatalytic water oxidation.. Catal. Sci. Technol.. 8, 4030–4043.

Gueret, R., Poulard L., Oshinowo M., Chauvin J., Dahmane M., Dupeyre G., et al. (2018). Challenging the [Ru(bpy)3]2+ Photosensitizer with a Triazatriangulenium Robust Organic Dye for Visible-Light-Driven Hydrogen Production in Water.. ACS Catal.. 8, 3792–3802.

Gerey, B., Gouré E., Fortage J., Pécaut J., & Collomb M-N. (2016). Manganese-calcium/strontium heterometallic compounds and their relevance for the oxygen-evolving center of photosystem II.. Coord. Chem. Rev.. 319, 1–24.

Gouré, E., Gerey B., Clemancey M., Pécaut J., Molton F., Latour J-M., et al. (2016). Intramolecular Electron Transfers Thwart Bistability in a Pentanuclear Iron Complex.. Inorg. Chem.. 55, 9178–9186.

Mognon, L., Mandal S., Castillo C. E., Fortage J., Molton F., Aromi G., et al. (2016). Synthesis, structure, spectroscopy and reactivity of new heterotrinuclear water oxidation catalysts.. Chem. Sci.. 7, 3304–3312.

Lo, W. K. C., Castillo C. E., Gueret R., Fortage J., Rebarz M., Sliwa M., et al. (2016). Synthesis, Characterization, and Photocatalytic H2-Evolving Activity of a Family of [Co(N4Py)(X)]n+ Complexes in Aqueous Solution.. Inorg. Chem.. 55, 4564–4581.

Kayanuma, M., Stoll T., Daniel C., Odobel F., Fortage J., Deronizer A., et al. (2015). A computational mechanistic investigation of hydrogen production in water using the [RhIII(dmbpy)2Cl2]+/[RuII(bpy)3]2+/ascorbic acid photocatalytic system.. Phys. Chem. Chem. Phys.. 17, 10497–10509.

Castillo, C. E., Gennari M., Stoll T., Fortage J., Deronizer A., Collomb M-N., et al. (2015). Visible Light-Driven Electron Transfer from a Dye-Sensitized p-Type NiO Photocathode to a Molecular Catalyst in Solution: Toward NiO-Based Photoelectrochemical Devices for Solar Hydrogen Production.. J. Phys. Chem. C. 119, 5806–5818.

Stoll, T., Castillo C. E., Kayanuma M., Sandroni M., Daniel C., Odobel F., et al. (2015). Photo-induced redox catalysis for proton reduction to hydrogen with homogeneous molecular systems using rhodium-based catalysts.. Coord. Chem. Rev.. 304-305, 20–37.

Martin-Diaconescu, V., Gennari M., Gerey B., Tsui E., Kanady J., Tran R., et al. (2015). Ca K-Edge XAS as a Probe of Calcium Centers in Complex Systems.. Inorg. Chem.. 54, 1283–1292.

Beckwith, M. A., Ames W., Vila F. D., Krewald V., Pantazis D. A., Mantel C., et al. (2015). How Accurately Can Extended X-ray Absorption Spectra Be Predicted from First Principles? Implications for Modeling the Oxygen-Evolving Complex in Photosystem II.. J. Am. Chem. Soc.. 137, 12815–12834.

Gerey, B., Gennari M., Gouré E., Pécaut J., Blackman A., Pantazis D. A., et al. (2015). Calcium and heterometallic manganese-calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations.. Dalt. Trans.. 44, 12757–12770.

Gueret, R., Castillo C. E., Rebarz M., Thomas F., Hargrove A-A., Pécaut J., et al. (2015). Cobalt(III) tetraaza-macrocyclic complexes as efficient catalyst for photoinduced hydrogen production in water: Theoretical investigation of the electronic structure of the reduced species and mechanistic insight.. J. Photochem. Photobiol. B Biol.. 152, 82–94.

Lombard, J., D Jose A., Castillo C. E., Pansu R., Chauvin J., Deronizer A., et al. (2014). Alternated bimetallic [Ru-M] (M = Fe2+, Zn2+) coordination polymers based on [Ru(bpy)3]2+ units connected to bis-terpyridine ligands: synthesis, electrochemistry and photophysics in solution or in thin film on electrodes.. J. Mater. Chem. C Mater. Opt. Electron. Devices. 2, 9824–9835.

Gimbert-Surinach, C., Albero J., Stoll T., Fortage J., Collomb M-N., Deronizer A., et al. (2014). Efficient and limiting reactions in aqueous light-induced hydrogen evolution systems using molecular catalysts and quantum dots.. J. Am. Chem. Soc.. 136, 7655–7661.

Stoll, T., Gennari M., Fortage J., Castillo C. E., Rebarz M., Sliwa M., et al. (2014). An efficient RuII-RhIII-RuII polypyridyl photocatalyst for visible-light-driven hydrogen production in aqueous solution.. Angew. Chemie, Int. Ed.. 53, 1654–1658.

Gennari, M., Legalite F., Zhang L., Pellegrin Y., Blart E., Fortage J., et al. (2014). Long-Lived Charge Separated State in NiO-Based p-Type Dye-Sensitized Solar Cells with Simple Cyclometalated Iridium Complexes.. J. Phys. Chem. Lett.. 5, 2254–2258.

Rich, J., Manrique E., Molton F., Duboc C., Collomb M-N., Rodriguez M., et al. (2014). Catalytic activity of chloro and triflate manganese(II) complexes in epoxidation reactions. Reusable catalytic systems for alkene epoxidation.. Eur. J. Inorg. Chem.. 2014, 2663–2670.

Gennari, M., Gerey B., Hall N., Pécaut J., Collomb M-N., Rouzières M., et al. (2014). A Bio-Inspired Switch Based on Cobalt(II) Disulfide/Cobalt(III) Thiolate Interconversion.. Angew. Chemie, Int. Ed.. 53, 5318–5321.

Horvath, R., Lombard J., Leprêtre J-C., Collomb M-N., Deronizer A., Chauvin J., et al. (2013). Excited-state spectroscopic investigations of multinuclear complexes based on [Ru(bpy)3]2+ moieties connected to 2,2'-bipyridine and 2,2';6',2''-terpyridine ligands.. Dalt. Trans.. 42, 16527–16537.

Varma, S., Castillo C. E., Stoll T., Fortage J., Blackman A., Molton F., et al. (2013). Efficient photocatalytic hydrogen production in water using a cobalt(III) tetraaza-macrocyclic catalyst: electrochemical generation of the low-valent Co(I) species and its reactivity toward proton reduction.. Phys. Chem. Chem. Phys.. 15, 17544–17552.

Retegan, M., Collomb M-N., Neese F., & Duboc C. (2013). A combined high-field EPR and quantum chemical study on a weakly ferromagnetically coupled dinuclear Mn(III) complex. A complete analysis of the EPR spectrum beyond the strong coupling limit.. Phys. Chem. Chem. Phys.. 15, 223–234.

Stoll, T., Gennari M., Serrano I., Fortage J., Chauvin J., Odobel F., et al. (2013). [RhIII(dmbpy)2Cl2]+ as a Highly Efficient Catalyst for Visible-Light-Driven Hydrogen Production in Pure Water: Comparison with Other Rhodium Catalysts.. Chem. - A Eur. J.. 19, 782–792.

Gennari, M., Gerey B., Hall N., Pécaut J., Vezin H., Collomb M-N., et al. (2012). Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex - the reactivity toward S-alkylation: an experimental and theoretical study.. Dalt. Trans.. 41, 12586–12594.

Castillo, C. E., Romain S., Retegan M., Leprêtre J-C., Chauvin J., Duboc C., et al. (2012). Visible-Light-Driven Generation of High-Valent Oxo-Bridged Dinuclear and Tetranuclear Manganese Terpyridine Entities Linked to Photoactive Ruthenium Units of Relevance to Photosystem II.. Eur. J. Inorg. Chem.. 2012, 5485–5499.

Gennari, M., Pécaut J., Collomb M-N., & Duboc C. (2012). A copper thiolate centre for electron transfer: mononuclear vs. dinuclear complexes.. Dalt. Trans.. 41, 3130–3133.

Roemelt, M., Beckwith M. A., Duboc C., Collomb M-N., Neese F., & DeBeer S.. (2012). Manganese K-Edge X-Ray Absorption Spectroscopy as a Probe of the Metal-Ligand Interactions in Coordination Compounds.. Inorg. Chem.. 51, 680–687.

Romain, S., Rich J., Sens C., Stoll T., Benet-Buchholz J., Llobet A., et al. (2011). Multireversible Redox Processes in Pentanuclear Bis(Triple-Helical) Manganese Complexes Featuring an Oxo-Centered triangular \MnII2MnIII($μ$3-O)\}5+ or \MnIIMnIII2($μ$3-O)\}6+ Core Wrapped by Two \MnII2(bpp)3\}-.}. Inorg. Chem.. 50, 8427–8436.

Romain, S., Duboc C., Retegan M., Leprêtre J-C., Blackman A., Deronizer A., et al. (2011). Electrochemical formation of bi- versus tetranuclear $μ$-oxo terpyridine manganese complexes in CH3CN. Influence of the terpyridine substituents.. Inorganica Chim. Acta. 374, 187–196.

Hall, N. A., Duboc C., Collomb M-N., Deronizer A., & Blackman A. (2011). Factors influencing mononuclear versus multinuclear coordination in a series of potentially hexadentate acyclic N6 ligands: the roles of flexibility and chelate ring size.. Dalt. Trans.. 40, 12075–12082.

Gennari, M., Retegan M., DeBeer S., Pécaut J., Neese F., Collomb M-N., et al. (2011). Experimental and Computational Investigation of Thiolate Alkylation in NiII and ZnII Complexes: Role of the Metal on the Sulfur Nucleophilicity.. Inorg. Chem.. 50, 10047–10055.

Beckwith, M. A., Roemelt M., Collomb M-N., Duboc C., Weng T-C., Bergmann U., et al. (2011). Manganese K$\beta$ X-ray Emission Spectroscopy As a Probe of Metal-Ligand Interactions.. Inorg. Chem.. 50, 8397–8409.

Collomb, M-N., & Deronzier A.. (2011). Manganese: inorganic & coordination chemistry.}. Encycl. Inorg. Bioinorg. Chem..

Gennari, M., Orio M., Pécaut J., Bothe E., Neese F., Collomb M-N., et al. (2011). Influence of Mixed Thiolate/Thioether versus Dithiolate Coordination on the Accessibility of the Uncommon +I and +III Oxidation States for the Nickel Ion: An Experimental and Computational Study.. Inorg. Chem.. 50, 3707–3716.

Gennari, M., Pécaut J., DeBeer S., Neese F., Collomb M-N., & Duboc C. (2011). A Fully Delocalized Mixed-Valence Bis-$μ$(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center.. Angew. Chemie, Int. Ed.. 50, 5662–5666, S5662/1–S5662/16.

Rich, J., Castillo C. E., Romero I., Rodriguez M., Duboc C., & Collomb M-N. (2010). Investigation of the Zero-Field Splitting in Six- and Seven-Coordinate Mononuclear MnII Complexes with N/O-Based Ligands by Combining EPR Spectroscopy and Quantum Chemistry.. Eur. J. Inorg. Chem.. 3658–3665.

Duboc, C., Ganyushin D., Sivalingam K., Collomb M-N., & Neese F. (2010). Systematic Theoretical Study of the Zero-Field Splitting in Coordination Complexes of Mn(III). Density Functional Theory versus Multireference Wave Function Approaches.. J. Phys. Chem. A. 114, 10750–10758.

Gennari, M., Orio M., Pécaut J., Neese F., Collomb M-N., & Duboc C. (2010). Reversible Apical Coordination of Imidazole between the Ni(III) and Ni(II) Oxidation States of a Dithiolate Complex: A Process Related to the Ni Superoxide Dismutase.. Inorg. Chem.. 49, 6399–6401.

Collomb, M-N., & Deronizer A. (2009). Electro- and Photoinduced Formation and Transformation of Oxido-Bridged Multinuclear Mn Complexes.. Eur. J. Inorg. Chem.. 2025–2046.

Romain, S., Baffert C., Duboc C., Leprêtre J-C., Deronizer A., & Collomb M-N. (2009). Mononuclear MnIII and MnIV Bis-terpyridine Complexes: Electrochemical Formation and Spectroscopic Characterizations.. Inorg. Chem.. 48, 3125–3131.

Romain, S., Duboc C., Neese F., Rivière E., Hanton L. R., Blackman A., et al. (2009). An unusual stable mononuclear MnIII bis-terpyridine complex exhibiting Jahn-Teller compression: electrochemical synthesis, physical characterisation and theoretical study.. Chem. - A Eur. J.. 15, 980–988.

Duboc, C., & Collomb M-N. (2009). Multifrequency high-field EPR investigation of a mononuclear manganese(iv) complex.. Chem. Commun. (Cambridge, United Kingdom). 2715–2717.

Rich, J., Rodriguez M., Romero I., Vaquer L., Sala X., Llobet A., et al. (2009). Mn(II) complexes containing the polypyridylic chiral ligand (-)-pineno[5,6]bipyridine. Catalysts for oxidation reactions.. Dalt. Trans.. 8117–8126.

Lombard, J., Boulaouche R., D Jose A., Chauvin J., Collomb M-N., & Deronizer A. (2009). Synthesis and properties of trinuclear polypyridyl complexes Ru(II)-Co(II)-Ru(II) and Ru(II)-Co(III)-Ru(II): Their photoinduced interconversion.. Inorganica Chim. Acta. 363, 234–242.

Duboc, C., Collomb M-N., & Neese F. (2009). Understanding the Zero-Field Splitting of Mononuclear Manganese(II) Complexes from Combined EPR Spectroscopy and Quantum Chemistry.. Appl. Magn. Reson.. 37, 229–245.

Baffert, C., Orio M., Pantazis D. A., Duboc C., Blackman A., Blondin G., et al. (2009). Trinuclear Terpyridine Frustrated Spin System with a MnIV3O4 Core: Synthesis, Physical Characterization, and Quantum Chemical Modeling of Its Magnetic Properties.. Inorg. Chem.. 48, 10281–10288.

Lombard, J., Leprêtre J-C., Damien Jouvenot, Deronizer A., & Collomb M-N. (2008). Electrochemical behaviour of interaction between Fe2+ with bisbipyridyl ligands in CH3CN. Application to an easy electrochemical procedure for tailoring films of Fe(bpy)32+ like cores (bpy = 2,2'-bipyridine).. New J. Chem.. 32, 1117–1123.

Lombard, J., Leprêtre J-C., Chauvin J., Collomb M-N., & Deronizer A. (2008). Photoredox vs. energy transfer in a Ru(ii)-Fe(ii) supramolecular complex built with an heteroditopic bipyridine-terpyridine ligand.. Dalt. Trans.. 658–666.

Duboc, C., Collomb M-N., Pécaut J., Deronizer A., & Neese F. (2008). Definition of magneto-structural correlations for the MnII ion.. Chem. - A Eur. J.. 14, 6498–6509.

Dubois, L., Pécaut J., Charlot M-F., Baffert C., Collomb M-N., Deronizer A., et al. (2008). Carboxylate ligands drastically enhance the rates of oxo exchange and hydrogen peroxide disproportionation by oxo manganese compounds of potential biological significance.. Chem. - A Eur. J.. 14, 3013–3025.

Duboc, C., Phoeung T., Damien Jouvenot, Blackman A., McClintock L. F., Pécaut J., et al. (2007). High-field EPR investigation of a series of mononuclear Mn(II) complexes doped into Zn(II) hosts.. Polyhedron. 26, 5243–5249.

Duboc, C., Phoeung T., Zein S., Pécaut J., Collomb M-N., & Neese F. (2007). Origin of the Zero-Field Splitting in Mononuclear Octahedral Dihalide MnII Complexes: An Investigation by Multifrequency High-Field Electron Paramagnetic Resonance and Density Functional Theory.. Inorg. Chem.. 46, 4905–4916.

Romain, S., Leprêtre J-C., Chauvin J., Deronizer A., & Collomb M-N. (2007). Di($μ$-oxo) Binuclear Manganese(III,IV) Poly(bipyridyl) Complexes Bearing Four Ruthenium(II) Photoactive Units: Synthesis, Characterization, and Photoinduced Electron-Transfer Properties.. Inorg. Chem.. 46, 2735–2743.

Collomb, M-N., Mantel C., Romain S., Duboc C., Leprêtre J-C., Pécaut J., et al. (2007). Redox-induced $μ$-acetato and $μ$-oxo core interconversions in dinuclear manganese tris(2-pyridylmethyl)amine (tpa) complexes: isolation and characterization of [Mn2III($μ$-O)($μ$-O2CCH3)(tpa)2]3+.. Eur. J. Inorg. Chem.. 3179–3187.

Romain, S., Baffert C., Dumas S., Chauvin J., Leprêtre J-C., Daveloose D., et al. (2006). Tetranuclear polybipyridyl complexes of RuII and MnII, their electro- and photoinduced transformation into di-$μ$-oxo MnIIIMnIV hexanuclear complexes.. Dalt. Trans.. 5691–5702.

Duboc, C., Astier-Perret V., Chen H., Pécaut J., Crabtree R. H., Brudvig G. W., et al. (2006). A multifrequency high-field EPR (9-285GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes.. Inorganica Chim. Acta. 359, 1541–1548.

Romero, I., Rodriguez M., Llobet A., Corbella M., Fernandez G., & Collomb M-N. (2005). EPR and magnetic properties of [Mn($μ$-Cl)2(bpy)]n: An unusual ferromagnetic interaction in a Mn(II) chloro-bridged polymer.. Inorganica Chim. Acta. 358, 4459–4465.

Chen, H., Collomb M-N., Duboc C., Blondin G., Rivière E., Faller J. W., et al. (2005). New Linear High-Valent Tetranuclear Manganese-Oxo Cluster Relevant to the Oxygen-Evolving Complex of Photosystem II with Oxo, Hydroxo, and Aqua Coordinated to a Single Mn(IV).. Inorg. Chem.. 44, 9567–9573.

Lombard, J., Romain S., Dumas S., Chauvin J., Collomb M-N., Daveloose D., et al. (2005). Tetranuclear polypyridyl complexes of RuII and FeII: Synthesis, electrochemical, photophysical and photochemical behaviour.. Eur. J. Inorg. Chem.. 3320–3330.

Baffert, C., Romain S., Richardot A., Leprêtre J-C., Lefebvre B., Deronzier A., et al. (2005). Electrochemical and Chemical Formation of [Mn4IVO5(terpy)4(H2O)2]6+, in Relation with the Photosystem II Oxygen-Evolving Center Model [Mn2III,IVO2(terpy)2(H2O)2]3+.. J. Am. Chem. Soc.. 127, 13694–13704.

Mantel, C., Chen H., Crabtree R. H., Brudvig G. W., Pécaut J., Collomb M-N., et al. (2005). High-spin chloro mononuclear MnIII complexes: a multifrequency high-field EPR study.. ChemPhysChem. 6, 541–546.

Baffert, C., Dumas S., Chauvin J., Leprêtre J-C., Collomb M-N., & Deronzier A.. (2005). Photoinduced oxidation of [Mn(L)3]2+ and [Mn2O2(L)4]3+ (L = 2,2'-bipyridine and 4,4'-dimethyl-2,2'-bipyridine) with the [Ru(bpy)3]2+/-aryl diazonium salt system.. Phys. Chem. Chem. Phys.. 7, 202–210.

Mantel, C., Philouze C., Collomb M-N., & Duboc C. (2004). Investigation of a neat versus magnetically diluted powdered mononuclear MnII complex by high-field and high-frequency EPR spectroscopy.. Eur. J. Inorg. Chem.. 3880–3886.

Mantel, C., Baffert C., Romero I., Deronzier A., Pécaut J., Collomb M-N., et al. (2004). Structural Characterization and Electronic Properties Determination by High-Field and High-Frequency EPR of a Series of Five-Coordinated Mn(II) Complexes.. Inorg. Chem.. 43, 6455–6463.

Baffert, C., Romero I., Pécaut J., Llobet A., Deronzier A., & Collomb M-N. (2004). Synthesis and structural characterization of five-, six-, and seven-coordinate mononuclear manganese(II) complexes with N-tridentate ligands.. Inorganica Chim. Acta. 357, 3430–3436.

Mantel, C., Hassan A. K., Pécaut J., Deronzier A., Collomb M-N., & Duboc C. (2003). A High-Frequency and High-Field EPR Study of New Azide and Fluoride Mononuclear Mn(III) Complexes.. J. Am. Chem. Soc.. 125, 12337–12344.

Dubois, L., Caspar R., Jacquamet L., Petit P-E., Charlot M-F., Baffert C., et al. (2003). Binuclear Manganese Compounds of Potential Biological Significance. Part 2. Mechanistic Study of Hydrogen Peroxide Disproportionation by Dimanganese Complexes: The Two Oxygen Atoms of the Peroxide End up in a Dioxo Intermediate.. Inorg. Chem.. 42, 4817–4827.

Lafolet, F., Chauvin J., Collomb M-N., Deronzier A., Laguitton-Pasquier H., Leprêtre J-C., et al. (2003). Photoinduced energy and electron transfer processes in heteropolynuclear polypyridyl complexes of Ru(II) and Fe(II).. Phys. Chem. Chem. Phys.. 5, 2520–2527.

Baffert, C., Collomb M-N., Deronzier A., Kjaergaard-Knudsen S., Latour J-M., Lund K. H., et al. (2003). Biologically relevant mono- and di-nuclear manganese II/III/IV complexes of mononegative pentadentate ligands.. Dalt. Trans.. 1765–1772.

Dubois, L., Xiang D-F., Tan X-S., Pécaut J., Jones P., Baudron S., et al. (2003). Binuclear Manganese Compounds of Potential Biological Significance. 1. Syntheses and Structural, Magnetic, and Electrochemical Properties of Dimanganese(II) and -(II,III) Complexes of a Bridging Unsymmetrical Phenolate Ligand.. Inorg. Chem.. 42, 750–760.

Mekmouche, Y., Hummel H., Ho R. Y. N., Jr. L. Que, Schunemann V., Thomas F., et al. (2002). Sulfide oxidation by hydrogen peroxide catalyzed by iron complexes: two metal centers are better than one.. Chem. - A Eur. J.. 8, 1196–1204.

Navarro, M., Collomb M-N., & Deronzier A.. (2002). Electrochemical preparation and properties of poly-cis-[\RuIII(L)2(OH2)\}2O]4+ (L=pyrrole-substituted-2,2'-bipyridine) modified electrodes. Their electroinduced transformations into poly-cis-[RuII(L)2(H2O)2]2+ and poly-cis-[RuII(L)2(CH3CN)2]2+ films. J. Electroanal. Chem.. 520, 150–156.

Romero, I., Dubois L., Collomb M-N., Deronzier A., Latour J-M., & Pecaut J.. (2002). A Dinuclear Manganese(II) Complex with the \Mn2($μ$-O2CCH3)3\}+ Core: Synthesis, Structure, Characterization, Electroinduced Transformation, and Catalase-like Activity.}. Inorg. Chem.. 41, 1795–1806.

Baffert, C., Collomb M-N., Deronzier A., Pécaut J., Limburg J., Crabtree R. H., et al. (2002). Two New Terpyridine Dimanganese Complexes: A Manganese(III,III) Complex with a Single Unsupported Oxo Bridge and a Manganese(III,IV) Complex with a Dioxo Bridge. Synthesis, Structure, and Redox Properties.. Inorg. Chem.. 41, 1404–1411.

Gorgy, K., Collomb M-N., Leprêtre J-C., Deronzier A., Duboc C., Ménage S., et al. (2001). An easy electrochemical procedure for tailoring thin films containing the [Fe(bpy)2(CH3CN)2]2+ and/or [Fe(bpy)3]2+-like cores (bpy=2,2'-bipyridine). Application to the design of a modified electrode with a supramolecular structure.. Electrochem. commun.. 3, 686–691.

Baffert, C., Chen H., Crabtree R. H., Brudvig G. W., & Collomb M-N. (2001). Electrochemical properties of [MnIII(terpy)(N3)3] (terpy = 2,2':6',2''-terpyridine) in CH3CN. Electrogeneration of dimanganese(II) di-$μ$-azido and dimanganese(IV) di-$μ$-oxo complexes.. J. Electroanal. Chem.. 506, 99–105.

Limburg, J., Vrettos J. S., Crabtree R. H., Brudvig G. W., de Paula J. C., Hassan A., et al. (2001). High-Frequency EPR Study of a New Mononuclear Manganese(III) Complex: [(terpy)Mn(N3)3] (terpy = 2,2':6',2''-Terpyridine).. Inorg. Chem.. 40, 1698–1703.

Romero, I., Collomb M-N., Deronzier A., Llobet A., Perret E., Pécaut J., et al. (2001). A novel dimanganese(II) complex with two chloride bridges - A two-electron oxidation system.. Eur. J. Inorg. Chem.. 69–72.

Dieguez, M., Collomb M-N., & Crabtree R. H. (2000). Organometallic color chemistry: studies on [FcCH=CHC5H4NCH2C6H4(tBu)]X (X = BPh4-, ClO4-).. J. Organomet. Chem.. 608, 146–152.

Collomb, M-N., Deronzier A., Gorgy K., & Lepretre J-C.. (2000). {{Chemical and electrochemical generation of [Fe(bpy)2(S)2]2+ (bpy = 2,2'-bipyridine. New J. Chem.. 24, 455–461.

Collomb, M-N., Deronzier A., Gorgy K., Leprêtre J-C., & Pecaut J.. (1999). Electrochemical properties of [FeIII(L)2Cl2][PF6] and [Fe2III,IIIO(L)4Cl2][PF6]2 [L = 2,2'-bipyridine (bpy) and 4,4'-dimethyl-2,2'-bipyridine (dmbpy)]. Crystal structures of the dmbpy derivatives.. New J. Chem.. 23, 785–790.

Collomb, M-N., Deronzier A., Richardot A., & Pecaut J.. (1999). {{Synthesis and characterization of a new kind of Mn2III,IV $μ$-oxo complex: [Mn2O2(terpy)2(H2O)2](NO3)3·6 H2O. New J. Chem.. 23, 351–354.

Berchet, L., Collomb M-N., Dubourdeaux P., Moneta W., Deronzier A., & Latour J-M.. (1998). A μ-oxo diiron complex of a new binucleating tetrapyridyl ligand.. Inorganica Chim. Acta. 282, 243–246.

Orillon, M., Chardon S., Collomb M-N., Deronzier A., Ziessel R., & Zsoldos D.. (1997). Carbon dioxide-reducing cathode..

Collomb, M-N., Deronzier A., Le Bozec H., & Navarro M.. (1996). Electrochemistry of cis-diaquo ruthenium(II) complexes with substituted 2,2'-bipyridine ligands in a non-coordinating solvent. Application to the elaboration of corresponding functionalized polypyrrole films.. J. Electroanal. Chem.. 410, 21–29.

Collomb, M-N., & Deronzier A.. (1995). Electrodes modified by polymeric films containing oxo manganese clusters.. J. Electroanal. Chem.. 391, 211–214.

Collomb, M-N., Deronzier A., & Ziessel R. (1994). Electrocatalytic reduction of CO2 in water on a polymeric [\Ru0(bpy)(CO)2\}n] (bpy = 2,2'-bipyridine) complex immobilized on carbon electrodes.}. J. Chem. Soc. Chem. Commun.. 189–191.

Collomb, M-N., Langlois S., & Genies E. (1994). Spectroelectrochemical behavior of poly(3-octylthiophene): application to electrochromic windows with polyaniline and iridium oxide.. J. Appl. Electrochem.. 24, 72–77.

Ménage, S., Collomb M-N., Lambeaux C., & Fontecave M.. (1994). Manganese(II) based oxidation of alkanes: generation of a high valent binuclear catalyst in situ.. J. Chem. Soc. Chem. Commun.. 1885–1886.

Chardon, S., Collomb M-N., Deronzier A., Ziessel R., & Zsoldos D.. (1994). Formation of Polymeric [\Ru0(bpy)(CO)2\}n] Films by Electrochemical Reduction of [Ru(bpy)2(CO)2](PF6)2: Its Implication in CO2 Electrocatalytic Reduction.}. Inorg. Chem.. 33, 4410–4412.

Collomb, M-N., Deronzier A., & Ziessel R. (1994). Electrocatalytic Reduction of Carbon Dioxide with Mono(bipyridine)carbonylruthenium Complexes in Solution or as Polymeric Thin Films.. Inorg. Chem.. 33, 2961–2967.

Collomb, M-N., Deronzier A., & Ziessel R. (1993). Electrochemical elaboration of thin films of poly[RuII(L)(CO)2Cl2] (L = 4-(2-pyrrol-1-ylethyl)-4'-methyl-2,2'-bipyridine or 4,4'-bis((3-pyrrol-1-ylpropyloxy)carbonyl)-2,2'-bipyridine): photochemical properties and photoimaging.. J. Phys. Chem.. 97, 5973–5979.

Collomb, M-N., Deronzier A., & Ziessel R. (1993). Electrochemical behavior of [RuII(L)(CO)2Cl2], [RuII(L)(CO)Cl3][Me4N] and [RuII(L)(CO)2(CH3CN)2][CF3SO3]2 complexes (L = 2,2'-bipyridine or 4,4'-isopropoxycarbonyl-2,2'-bipyridine).. J. Electroanal. Chem.. 350, 43–55.

Collomb, M-N., Deronzier A., & Ziessel R. (1993). Photochemical reactivity of [RuII(L)(CO)2Cl2] and [Me4N] [RuII(L)(CO)Cl3] (L = 2,2'-bipyridine or 4,4'-di(isopropoxycarbonyl)-2,2'-bipyridine) in acetonitrile and the redox properties of the resulting new complexes.. J. Organomet. Chem.. 444, 191–198.

Genies, E. M., Lapkowski M., Noel P., Langlois S., Collomb M-N., & Miquelino F. (1991). Recent results on polyanilines, electrochemistry, EPR-substituted derivatives, applications, displays, etc.. Synth. Met.. 43, 2847–2852.

Collomb, M-N., Deronzier A., & Ziessel R. (1991). Electrochemical characterization of [RuII(bpy)(CO)2Cl2] (bpy = 2,2'-bipyridine). Isolation of a new complex: [RuII(bpy)(CO)Cl2][Me4N].. J. Electroanal. Chem. Interfacial Electrochem.. 319, 347–353.

Marie-Noëlle Collomb is Director of Research at the Centre National de la Recherche Scientifique (CNRS) in Grenoble (France) and leader of the group “Artificial Photosynthesis and Energy Vectors” in the Chimie Inorganique Rédox laboratory of the Département de Chimie Moléculaire at the University Grenoble Alpes (UGA). She obtained her Master degree in electrochemistry in 1990 from the Institut Polytechnique of Grenoble and her PhD in chemistry in 1993 from the UGA working on the electrocatalytic carbon dioxide reduction with molecular complexes under the mentorship of Alain Deronzier. After a year postdoctoral fellowship with Prof. Marc Fontecave at UGA, she joined the CNRS in 1994 as research scientist and was promoted Director of Research in 2007. In 1998-1999, she was CNRS research associate in the groups of Professors Robert H. Crabtree and Gary W. Brudvig at Yale University (New Haven, USA) (NATO fellowship), working on manganese chemistry. She has published over 105 papers in peer-reviewed journal.

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