JEROME FORTAGE
Chargé de recherche (CNRS)
Affiliation
Centre national de la recherche scientifique
Équipe de recherche
DCM-EMPRE
Domaines de recherche
electrocatalytic and photocatalytic reaction for water splitting and CO2 reduction
Disciplines scientifiques
Chimie physique, théorique et analytique
Habilitation à diriger des recherches
Développement de photosystèmes artificiels pour la conversion de l’énergie solaire en énergie chimique
from 01/11/2010 to 12/07/2017
from 01/11/2010 to 12/07/2017
Thèse
Synthèses et caractérisations d’édifices bisporphyriniques pour la séparation photo-induite de charges et Sensibilisation par photo-injection de lacunes électroniques dans des nanoparticules d’oxyde de nickel par des pérylènes imides
sous la direction de M. Fabrice Odobel, Directeur de Recherches CNRS
from 01/10/2003 to 08/12/2006
sous la direction de M. Fabrice Odobel, Directeur de Recherches CNRS
from 01/10/2003 to 08/12/2006
Google scholar-Jérôme Fortage
ORCID-Jérôme Fortage
ORCID-Jérôme Fortage
Gouré, E., Gerey B., Astudillo C. N., Pécaut J., Sirach S., Molton F., et al.
(2021). Self-Assembled Heterometallic Complexes by Incorporation of Calcium or Strontium Ion into a Manganese(II) 12-Metallacrown-3 Framework Supported by a Tripodal Ligand with Pyridine-Carboxylate Motifs: Stability in Their Manganese(III) Oxidized Form.
Inorganic Chemistry. 60, 7922-7936.
Morales, D. V., Astudillo C. N., Anastasoaie V., Dautreppe B., Urbano B. F., Rivas B. L., et al.
(2021). A cobalt oxide–polypyrrole nanocomposite as an efficient and stable electrode material for electrocatalytic water oxidation.
Sustainable Energy & Fuels. 5(18),
Morales, D. V., Astudillo C. N., Anastasoaie V., Dautreppe B., Urbano B. F., Rivas B. L., et al.
(2021). A cobalt oxide–polypyrrole nanocomposite as an efficient and stable electrode material for electrocatalytic water oxidation.
Sustainable Energy Fuels. 5, 4710-4723.
Collomb, M-N., Morales D. V., Astudillo C. N., Dautreppe B., & Fortage J.
(2020). Hybrid photoanodes for water oxidation combining a molecular photosensitizer with a metal oxide oxygen-evolving catalyst.
Sustainable Energy Fuels. 4, 31-49.
Gouré, E., Gerey B., Molton F., Pécaut J., Clérac R., Thomas F., et al.
(2020). Seven Reversible Redox Processes in a Self-Assembled Cobalt Pentanuclear Bis(triple-stranded helicate): Structural, Spectroscopic, and Magnetic Characterizations in the CoICoII4, CoII5, and CoII3CoIII2 Redox States.
Inorganic Chemistry. 59, 9196-9205.
Costentin, C., Fortage J., & Collomb M-N.
(2020). Electrophotocatalysis: Cyclic Voltammetry as an Analytical Tool.
The Journal of Physical Chemistry Letters. 11, 6097-6104.
Gueret, R., Castillo C. E., Rebarz M., Thomas F., Sliwa M., Chauvin J., et al.
(2019). Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species.
Inorganic Chemistry. 58, 9043-9056.
Gueret, R., Poulard L., Oshinowo M., Chauvin J., Dahmane M., Dupeyre G., et al.
(2018). Challenging the [Ru(bpy)3]2+ Photosensitizer with a Triazatriangulenium Robust Organic Dye for Visible-Light-Driven Hydrogen Production in Water.
ACS Catalysis. 8, 3792-3802.
Castillo, C. E., Stoll T., Sandroni M., Gueret R., Fortage J., Kayanuma M., et al.
(2018). Electrochemical Generation and Spectroscopic Characterization of the Key Rhodium(III) Hydride Intermediates of Rhodium Poly(bipyridyl) H2-Evolving Catalysts.
Inorganic Chemistry. 57, 11225-11239.
Morales, D. V., Astudillo C. N., Lattach Y., Urbano B. F., Pereira E., Rivas B. L., et al.
(2018). Nickel oxide-polypyrrole nanocomposite electrode materials for electrocatalytic water oxidation..
Catal. Sci. Technol.. 8, 4030–4043.
Gueret, R., Poulard L., Oshinowo M., Chauvin J., Dahmane M., Dupeyre G., et al.
(2018). Challenging the [Ru(bpy)3]2+ Photosensitizer with a Triazatriangulenium Robust Organic Dye for Visible-Light-Driven Hydrogen Production in Water..
ACS Catal.. 8, 3792–3802.
Gerey, B., Gouré E., Fortage J., Pécaut J., & Collomb M-N.
(2016). Manganese-calcium/strontium heterometallic compounds and their relevance for the oxygen-evolving center of photosystem II..
Coord. Chem. Rev.. 319, 1–24.
Mognon, L., Mandal S., Castillo C. E., Fortage J., Molton F., Aromi G., et al.
(2016). Synthesis, structure, spectroscopy and reactivity of new heterotrinuclear water oxidation catalysts..
Chem. Sci.. 7, 3304–3312.
Lo, W. K. C., Castillo C. E., Gueret R., Fortage J., Rebarz M., Sliwa M., et al.
(2016). Synthesis, Characterization, and Photocatalytic H2-Evolving Activity of a Family of [Co(N4Py)(X)]n+ Complexes in Aqueous Solution..
Inorg. Chem.. 55, 4564–4581.
Gerey, B., Gennari M., Gouré E., Pécaut J., Blackman A., Pantazis D. A., et al.
(2015). Calcium and heterometallic manganese-calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations..
Dalt. Trans.. 44, 12757–12770.
Gueret, R., Castillo C. E., Rebarz M., Thomas F., Hargrove A-A., Pécaut J., et al.
(2015). Cobalt(III) tetraaza-macrocyclic complexes as efficient catalyst for photoinduced hydrogen production in water: Theoretical investigation of the electronic structure of the reduced species and mechanistic insight..
J. Photochem. Photobiol. B Biol.. 152, 82–94.
Kayanuma, M., Stoll T., Daniel C., Odobel F., Fortage J., Deronizer A., et al.
(2015). A computational mechanistic investigation of hydrogen production in water using the [RhIII(dmbpy)2Cl2]+/[RuII(bpy)3]2+/ascorbic acid photocatalytic system..
Phys. Chem. Chem. Phys.. 17, 10497–10509.
Castillo, C. E., Gennari M., Stoll T., Fortage J., Deronizer A., Collomb M-N., et al.
(2015). Visible Light-Driven Electron Transfer from a Dye-Sensitized p-Type NiO Photocathode to a Molecular Catalyst in Solution: Toward NiO-Based Photoelectrochemical Devices for Solar Hydrogen Production..
J. Phys. Chem. C. 119, 5806–5818.
Stoll, T., Castillo C. E., Kayanuma M., Sandroni M., Daniel C., Odobel F., et al.
(2015). Photo-induced redox catalysis for proton reduction to hydrogen with homogeneous molecular systems using rhodium-based catalysts..
Coord. Chem. Rev.. 304-305, 20–37.
Lattach, Y., Fortage J., Deronizer A., & Moutet J-C.
(2015). Polypyrrole-Ru(2,2'-bipyridine)32+/MoSx structured composite film as a photocathode for the hydrogen evolution reaction..
ACS Appl. Mater. Interfaces. 7, 4476–4480.
Gimbert-Surinach, C., Albero J., Stoll T., Fortage J., Collomb M-N., Deronizer A., et al.
(2014). Efficient and limiting reactions in aqueous light-induced hydrogen evolution systems using molecular catalysts and quantum dots..
J. Am. Chem. Soc.. 136, 7655–7661.
Stoll, T., Gennari M., Fortage J., Castillo C. E., Rebarz M., Sliwa M., et al.
(2014). An efficient RuII-RhIII-RuII polypyridyl photocatalyst for visible-light-driven hydrogen production in aqueous solution..
Angew. Chemie, Int. Ed.. 53, 1654–1658.
Gennari, M., Legalite F., Zhang L., Pellegrin Y., Blart E., Fortage J., et al.
(2014). Long-Lived Charge Separated State in NiO-Based p-Type Dye-Sensitized Solar Cells with Simple Cyclometalated Iridium Complexes..
J. Phys. Chem. Lett.. 5, 2254–2258.
Varma, S., Castillo C. E., Stoll T., Fortage J., Blackman A., Molton F., et al.
(2013). Efficient photocatalytic hydrogen production in water using a cobalt(III) tetraaza-macrocyclic catalyst: electrochemical generation of the low-valent Co(I) species and its reactivity toward proton reduction..
Phys. Chem. Chem. Phys.. 15, 17544–17552.
Stoll, T., Gennari M., Serrano I., Fortage J., Chauvin J., Odobel F., et al.
(2013). [RhIII(dmbpy)2Cl2]+ as a Highly Efficient Catalyst for Visible-Light-Driven Hydrogen Production in Pure Water: Comparison with Other Rhodium Catalysts..
Chem. - A Eur. J.. 19, 782–792.
Castillo, C. E., Romain S., Retegan M., Leprêtre J-C., Chauvin J., Duboc C., et al.
(2012). Visible-Light-Driven Generation of High-Valent Oxo-Bridged Dinuclear and Tetranuclear Manganese Terpyridine Entities Linked to Photoactive Ruthenium Units of Relevance to Photosystem II..
Eur. J. Inorg. Chem.. 2012, 5485–5499.
Both energy transfer and photo-induced electron transfer play a key role in the photochemical processes of natural photosynthesis, but also in many molecular devices with applications in photovoltaics, molecular electronics, optical information storage or photocatalysis.
These photo-induced processes are the main thread of my research career. Based on a related concept of photo-induced charge separation, my thesis work at the University of Nantes under the supervision of Dr. Fabrice Odobel (October 2003 - December 2006) was divided into two distinct parts: the design of artificial photosystems in the form of molecular dyads containing porphyrins and phthalocyanines and the elaboration of new photovoltaic devices, of the Grätzel type, via the grafting of perylene onto a p-type semiconductor (NiO) or n-type semiconductor (TiO2).
In addition, during my first post-doctoral year at the University of Newcastle (UK) under the supervision of Prof. Andrew Benniston (January 2007-January 2008), I was led to develop molecular switches based on other types of photochemical processes such as photo-induced opening and closing of spiropyrans.
Then, during the three post-doctoral years that followed at “Université Paris Descartes” under the supervision of Dr. Philippe Lainé and Dr. Valérie Marvaud (February 2008 to October 2010), I designed new molecular architectures to mimic some photochemical processes operating during natural photosynthesis of plants such as photo-induced charge separation; these architectures being composed of ruthenium or osmium complexes, as well as analogues of viologens.
Finally, since I joined the Department of Molecular Chemistry in the “Université Grenoble Alpes” (DCM - UMR CNRS-UGA 5250) as a CNRS Researcher (chargé de recherche) in 2010, I am interested in the development of molecular or hybrid (molecular/inorganic) systems to conduct electro or photo-catalytic reactions for the dissociation of water into O2 and H2, but also for the reduction of CO2 into industrially valuable products (i.e. CO, HCOOH).
In addition, during my first post-doctoral year at the University of Newcastle (UK) under the supervision of Prof. Andrew Benniston (January 2007-January 2008), I was led to develop molecular switches based on other types of photochemical processes such as photo-induced opening and closing of spiropyrans.
Then, during the three post-doctoral years that followed at “Université Paris Descartes” under the supervision of Dr. Philippe Lainé and Dr. Valérie Marvaud (February 2008 to October 2010), I designed new molecular architectures to mimic some photochemical processes operating during natural photosynthesis of plants such as photo-induced charge separation; these architectures being composed of ruthenium or osmium complexes, as well as analogues of viologens.
Finally, since I joined the Department of Molecular Chemistry in the “Université Grenoble Alpes” (DCM - UMR CNRS-UGA 5250) as a CNRS Researcher (chargé de recherche) in 2010, I am interested in the development of molecular or hybrid (molecular/inorganic) systems to conduct electro or photo-catalytic reactions for the dissociation of water into O2 and H2, but also for the reduction of CO2 into industrially valuable products (i.e. CO, HCOOH).
CONTACT
Bâtiment : Chimie C
Bureau : 313bis
0476514403