Site du DCM - Université Grenoble Alpes

JEROME CHAUVIN

Maître de conférences

Affiliation

Université Grenoble Alpes

Équipe de recherche

DCM-CIRE

Domaines de recherche

Photophysics and Photoredox chemistry of metallic complexes, molecular photocatalysis, photoelectrode.

Disciplines scientifiques

Chimie physique, théorique et analytique

Habilitation à diriger des recherches

Responsabilités

Responsable Licence de Physique et Chimie, UFR de Chimie et Biologie
Responsable UE Structure de la matière, DLST

Enseignement

Structure de la matière: Licence, semestre 1
Chimie générale: Licence, semestre 2
Cinétique chimique: Licence, semestre 5
Photophysique, Photochimie et Photoredox: Master, semestre 2 et semestre 3

Farran, R., Le-Quang L., Mouesca J-M., Maurel V., Damien Jouvenot, Loiseau F., et al. (2019). [Cr(ttpy)2]3+ as a multi-electron reservoir for photoinduced charge accumulation. Dalton Trans.. 48, 6800-6811.

Médard, J., Combellas C., Kanoufi F., Pinson J., Chauvin J., & Deronzier A. (2018). Patterning Surfaces through Photografting of Iodonium Salts. The Journal of Physical Chemistry C. 122, 19722-19730.

Gueret, R., Poulard L., Oshinowo M., Chauvin J., Dahmane M., Dupeyre G., et al. (2018). Challenging the [Ru(bpy)3]2+ Photosensitizer with a Triazatriangulenium Robust Organic Dye for Visible-Light-Driven Hydrogen Production in Water. ACS Catalysis. 8, 3792-3802.

Le-Quang, L., Farran R., Lattach Y., Bonnet H., Jamet H., Guerente L., et al. (2018). Photoactive Molecular Dyads [Ru(bpy)3–M(ttpy)2]n+ on Gold (M = Co(III), Zn(II)): Characterization, Intrawire Electron Transfer, and Photoelectric Conversion. Langmuir. 34, 5193–5203.

Farran, R., Le Quang L., Damien Jouvenot, Loiseau F., Pansu R., Deronizer A., et al. (2017). Photoelectrochemical behavior of multimetallic assemblies based on [Ru(bpy)3]2+-terpyridine building block: [Ru(II)-M-Ru(II)]n+ in solution and [Ru(II)-M]n+ dyad anchored on ITO (M = Co(III), Fe(II)).. Inorganica Chim. Acta. 454, 197–207.

Castaldelli, E., Jayawardena K. D. G. Imalka, Cox D. C., Clarkson G. J., Walton R. I., Le-Quang L., et al. (2017). Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework. Nature Communications. 8(1),

Castillo, C. E., Armstrong J., Laurila E., Oresmaa L., Haukka M., Chauvin J., et al. (2016). Electro- and Photo-driven Reduction of CO2 by a trans-(Cl)-[Os(diimine)(CO)2Cl2] Precursor Catalyst: Influence of the Diimine Substituent and Activation Mode on CO/HCOO- Selectivity.. ChemCatChem. 8, 2667–2677.

Farran, R., Damien Jouvenot, Gennaro B., Loiseau F., Chauvin J., & Deronizer A. (2016). Photoinduced Charge Separation within Metallo-supramolecular Wires Built around a [Ru(bpy)3]2+-Bisterpyridine Linear Entity.. ACS Appl. Mater. Interfaces. 8, 16136–16146.

Chauvire, T., Mouesca J-M., Gasparutto D., Ravanat J-L., Lebrun C., Gromova M., et al. (2015). Redox Photocatalysis with Water-Soluble Core-Shell CdSe-ZnS Quantum Dots.. J. Phys. Chem. C. 119, 17857–17866.

Lombard, J., D Jose A., Castillo C. E., Pansu R., Chauvin J., Deronizer A., et al. (2014). Alternated bimetallic [Ru-M] (M = Fe2+, Zn2+) coordination polymers based on [Ru(bpy)3]2+ units connected to bis-terpyridine ligands: synthesis, electrochemistry and photophysics in solution or in thin film on electrodes.. J. Mater. Chem. C Mater. Opt. Electron. Devices. 2, 9824–9835.

Farran, R., Damien Jouvenot, Loiseau F., Chauvin J., & Deronizer A. (2014). Photoelectric conversion at a [Ru(bpy)3]2+-based metallic triad anchored on ITO surface.. Dalt. Trans.. 43, 12156–12159.

Horvath, R., Lombard J., Leprêtre J-C., Collomb M-N., Deronizer A., Chauvin J., et al. (2013). Excited-state spectroscopic investigations of multinuclear complexes based on [Ru(bpy)3]2+ moieties connected to 2,2'-bipyridine and 2,2';6',2''-terpyridine ligands.. Dalt. Trans.. 42, 16527–16537.

Liatard, S., Chauvin J., Damien Jouvenot, Loiseau F., & Deronizer A. (2013). Photoinduced Energy vs Electron Transfer Between Fe(II) and Ru(II) Bisterpyridyl Complexes in Solution and Grafted on a Gold Surface.. J. Phys. Chem. C. 117, 20431–20439.

Stoll, T., Gennari M., Serrano I., Fortage J., Chauvin J., Odobel F., et al. (2013). [RhIII(dmbpy)2Cl2]+ as a Highly Efficient Catalyst for Visible-Light-Driven Hydrogen Production in Pure Water: Comparison with Other Rhodium Catalysts.. Chem. - A Eur. J.. 19, 782–792.

Liatard, S., Chauvin J., Balestro F., Damien Jouvenot, Loiseau F., & Deronizer A. (2012). An Original Electrochemical Method for Assembling Multilayers of Terpyridine-Based Metallic Complexes on a Gold Surface.. Langmuir. 28, 10916–10924.

Castillo, C. E., Romain S., Retegan M., Leprêtre J-C., Chauvin J., Duboc C., et al. (2012). Visible-Light-Driven Generation of High-Valent Oxo-Bridged Dinuclear and Tetranuclear Manganese Terpyridine Entities Linked to Photoactive Ruthenium Units of Relevance to Photosystem II.. Eur. J. Inorg. Chem.. 2012, 5485–5499.

Jacq, J., Tsekhanovich S., Orio M., Einhorn C., Einhorn J., Bessieres B., et al. (2012). Structure and dynamics of the excited states of 1,3-diarylisobenzofurans: an experimental and theoretical study.. Photochem. Photobiol.. 88, 633–638.

Four, M., Riehl D., Mongin O., Blanchard-Desce M., Lawson-Daku L. Max, Moreau J., et al. (2011). A novel ruthenium(II) complex for two-photon absorption-based optical power limiting in the near-IR range.. Phys. Chem. Chem. Phys.. 13, 17304–17312.

Guerin, J., Aronica C., Boeuf G., Chauvin J., Moreau J., & Lemercier G.. (2011). Optical properties of new 5-(4-phenylethynyl)-substituted-1,10-phenanthroline derivatives.. J. Lumin.. 131, 2668–2673.

Chauvin, J., Lafolet F., Chardon S., Deronizer A., Jakonen M., & Haukka M.. (2011). Towards New Molecular Photocatalysts for CO2 Reduction: Photo-Induced Electron Transfer versus CO Dissociation within [Os(NN)(CO)2Cl2] Complexes.. Chem. - A Eur. J.. 17, 4313–4322.

Dinda, J., Liatard S., Chauvin J., Damien Jouvenot, & Loiseau F. (2011). Electronic and geometrical manipulation of the excited state of bis-terdentate homo- and heteroleptic ruthenium complexes.. Dalt. Trans.. 40, 3683–3688.

Aronica, C., Guerin J., Chauvin J., Robert V., & Lemercier G.. (2010). Optical properties of a donor-acceptor-substituted "hemi-cruciform" catechol derivative.. J. Photochem. Photobiol. A Chem.. 211, 147–151.

Lombard, J., Boulaouche R., D Jose A., Chauvin J., Collomb M-N., & Deronizer A. (2009). Synthesis and properties of trinuclear polypyridyl complexes Ru(II)-Co(II)-Ru(II) and Ru(II)-Co(III)-Ru(II): Their photoinduced interconversion.. Inorganica Chim. Acta. 363, 234–242.

Aronica, C., Venancio-Marques A., Chauvin J., Robert V., & Lemercier G.. (2009). A Rational Design of Catechol-Based Compounds: An Experimental and Theoretical Study of Optical Properties.. Chem. - A Eur. J.. 15, 5047–5055.

Dumas, S., Grabchev I., Stoikova P., Chauvin J., & Chovelon J-M.. (2009). Synthesis of benzanthron derivatives for selective detection by fluorescence of copper ions.. J. Photochem. Photobiol. A Chem.. 201, 237–242.

Lombard, J., Leprêtre J-C., Chauvin J., Collomb M-N., & Deronizer A. (2008). Photoredox vs. energy transfer in a Ru(ii)-Fe(ii) supramolecular complex built with an heteroditopic bipyridine-terpyridine ligand.. Dalt. Trans.. 658–666.

Girardot, C., Cao B., Mulatier J-C., Baldeck P. L., Chauvin J., Riehl D., et al. (2008). Ruthenium(II) complexes for two-photon absorption-based optical power limiting.. ChemPhysChem. 9, 1531–1535.

David, E., Lejeune J., Pellet-Rostaing S., Schulz J., Lemaire M., Chauvin J., et al. (2008). Synthesis of fluorescent rhodamine dyes using an extension of the Heck reaction.. Tetrahedron Lett.. 49, 1860–1864.

Girardot, C., Lemercier G., Mulatier J.-C.., Andraud C., Chauvin J., & Baldeck P. L. (2008). Novel 5-(oligofluorenyl)-1,10-phenanthroline type ligands: synthesis, linear and two-photon absorption properties.. Tetrahedron Lett.. 49, 1753–1758.

Jakonen, M., Hirva P., Haukka M., Chardon S., Lafolet F., Chauvin J., et al. (2007). An alternative synthesis method for [Os(NN)(CO)2X2] complexes (NN = 2,2'-bipyridine, 4,4'-dimethyl-2,2'-bipyridine; X = Cl, Br, I). Electrochemical and photochemical properties and behavior.. Dalt. Trans.. 3314–3324.

Girardot, C., Lemercier G., Mulatier J.-C.., Chauvin J., Baldeck P. L., & Andraud C. (2007). Novel ruthenium(II) and zinc(II) complexes for two-photon absorption related applications.. Dalt. Trans.. 3421–3426.

Romain, S., Leprêtre J-C., Chauvin J., Deronizer A., & Collomb M-N. (2007). Di($μ$-oxo) Binuclear Manganese(III,IV) Poly(bipyridyl) Complexes Bearing Four Ruthenium(II) Photoactive Units: Synthesis, Characterization, and Photoinduced Electron-Transfer Properties.. Inorg. Chem.. 46, 2735–2743.

Romain, S., Baffert C., Dumas S., Chauvin J., Leprêtre J-C., Daveloose D., et al. (2006). Tetranuclear polybipyridyl complexes of RuII and MnII, their electro- and photoinduced transformation into di-$μ$-oxo MnIIIMnIV hexanuclear complexes.. Dalt. Trans.. 5691–5702.

Haddour, N., Chauvin J., Gondran C., & Cosnier S. (2006). Photoelectrochemical Immunosensor for Label-Free Detection and Quantification of Anti-cholera Toxin Antibody.. J. Am. Chem. Soc.. 128, 9693–9698.

Lombard, J., Romain S., Dumas S., Chauvin J., Collomb M-N., Daveloose D., et al. (2005). Tetranuclear polypyridyl complexes of RuII and FeII: Synthesis, electrochemical, photophysical and photochemical behaviour.. Eur. J. Inorg. Chem.. 3320–3330.

Baffert, C., Dumas S., Chauvin J., Leprêtre J-C., Collomb M-N., & Deronzier A.. (2005). Photoinduced oxidation of [Mn(L)3]2+ and [Mn2O2(L)4]3+ (L = 2,2'-bipyridine and 4,4'-dimethyl-2,2'-bipyridine) with the [Ru(bpy)3]2+/-aryl diazonium salt system.. Phys. Chem. Chem. Phys.. 7, 202–210.

Lafolet, F., Chauvin J., Collomb M-N., Deronzier A., Laguitton-Pasquier H., Leprêtre J-C., et al. (2003). Photoinduced energy and electron transfer processes in heteropolynuclear polypyridyl complexes of Ru(II) and Fe(II).. Phys. Chem. Chem. Phys.. 5, 2520–2527.

My currently active area of interest is focused on the properties of polymetallic assemblies in which a light-absorbing group with a long excited-state lifetime (commonly a Ru(II)-polypyridyl unit) is attached by a suitable bridging ligand to a metal fragment, in order to use the excited-state energy of the photosensitiser to drive a redox reaction. These molecular systems are of particular interest in a variety of fields ranging from solar energy conversion to display devices when immobilized on electrodes. I am especially engaged in the use of of time-resolved spectroscopy to investigate the photoinduced energy and electron transfer process within such assemblies and in the resulting photoredox behavior.

Education:

Habilitation à diriger des recherches (2011), University of Grenoble, France
Visiting researcher (2011-6 months), Arizona State University at Tempe (USA) with Pr. D. Gust, T. and A. Moore
Postdoctoral position (1999-2001) with Pr Masahiro Irie, University of Kyushu, Japan
PhD, Ecole Normale Supérieure de Cachan (1995-1998), supervision : Pr. J. Delaire, K. Nakatani

CONTACT

0476514137

Jerome.Chauvin@univ-grenoble-alpes.fr

Site web :

Département de chimie moléculaire

Formulaire de recherche

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