Site du DCM - Université Grenoble Alpes

DAVID MARTIN

Directeur de recherche (CNRS)

Affiliation

Centre national de la recherche scientifique

Équipe de recherche

DCM-CIRE

Domaines de recherche

Unusual redox-active organic radical patterns

Habilitation à diriger des recherches

ORCID ID: 0000-0002-3257-9876
Research ID: N-7040-2015
Website -- LINK TO MY RESEARCH --

Peltier, J. L., Serrato M. R., Théry V., Pécaut J., Tomás-Mendivil E., Bertrand G., et al. (2023). An air-stable radical with a redox-chameleonic amide. Chem. Commun.. 59, 595-598.

Théry, V., Molton F., Sirach S., Tillet N., Pécaut J., Tomás-Mendivil E., et al. (2022). The curious case of a sterically crowded Stenhouse salt. Chem. Sci.. 13, 9755-9760.

Delfau, L., Nichilo S., Molton F., Broggi J., Tomás-Mendivil E., & Martin D. (2021). Critical Assessment of the Reducing Ability of Breslow-type Derivatives and Implications for Carbene-Catalyzed Radical Reactions. Angewandte Chemie International Edition. 60, 26783–26789.

Tomás-Mendivil, E., Devillard M., Regnier V., Pécaut J., & Martin D. (2020). Air-Stable Oxyallyl Patterns and a Switchable N-Heterocyclic Carbene. Angewandte Chemie International Edition. 59, 11516-11520.

Peltier, J. L., Soleilhavoup M., Martin D., Jazzar R., & Bertrand G. (2020). Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. Journal of the American Chemical Society. 142, 16479-16485.

Regnier, V., Romero E. A., Molton F., Jazzar R., Bertrand G., & Martin D. (2019). What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis?.. J. Am. Chem. Soc.. 141, 1109–1117.

Devillard, M., Regnier V., Pécaut J., & Martin D. (2019). Stable dicationic dioxoliums and fate of their dioxolyl radicals. Org. Chem. Front.. -.

Mahoney, J. K., Regnier V., Romero E. A., Molton F., Royal G., Jazzar R., et al. (2018). The serendipitous discovery of a readily available redox-bistable molecule derived from cyclic(alkyl)(amino)carbenes.. Org. Chem. Front.. 5, 2073–2078.

Tripathi, M., Regnier V., Ziani Z., Devillard M., Philouze C., & Martin D. (2018). Metal free oxidation of vinamidine derivatives: a simple synthesis of alpha-keto-beta-diimine ligands. RSC Adv.. 8, 38346–38350.

Devillard, M., Regnier V., Tripathi M., & Martin D. (2018). A computational study of the interplay of steric and electronic effects in the stabilization of 1,3-(diamino)oxyallyls. Journal of Molecular Structure.

Mahoney, J. K., Jazzar R., Royal G., Martin D., & Bertrand G.. (2017). The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals.. Chem. - A Eur. J.. 23, 6206–6212.

Regnier, V., Planet Y., Moore C. E., Pécaut J., Philouze C., & Martin D. (2017). Stable Di‐ and Tri‐coordinated Carbon(II) Supported by an Electron‐Rich β‐Diketiminate Ligand. Angew. Chemie, Int. Ed.. 56, 1031–1035.

Tripathi, M., Regnier V., Lincheneau C., & Martin D. (2017). Investigation of the full reversal of selectivity in the reaction of aniline with 1,3-dichloro-1,3-bis(dimethylamino)vinamidinium salts. New J. Chem.. 41, 15016-15020.

Regnier, V., Molton F., Philouze C., & Martin D. (2016). An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents.. Chem. Commun. (Cambridge, United Kingdom). 52, 11422–11425.

Hu, X., Martin D., & Bertrand G.. (2016). Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(I) complexes.. New J. Chem.. 40, 5993–5996.

Martin, D., Marx V. M., Grubbs R. H., & Bertrand G.. (2016). A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand.. Adv. Synth. Catal.. 358, 965–969.

Mahoney, J. K., Martin D., Thomas F., Moore C. E., Rheingold A. L., & Bertrand G.. (2015). Air-Persistent Monomeric (Amino)(carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes.. J. Am. Chem. Soc.. 137, 7519–7525.

Regnier, V., & Martin D. (2015). The quest for observation and isolation of oxyallyl derivatives.. Org. Chem. Front.. 2, 1536–1545.

Martin, D., Canac Y., Lavallo V., & Bertrand G.. (2014). Comparative Reactivity of Different Types of Stable Cyclic and Acyclic Mono- and Diamino Carbenes with Simple Organic Substrates.. J. Am. Chem. Soc.. 136, 5023–5030.

Hu, X., Martin D., Melaimi M., & Bertrand G.. (2014). Gold-Catalyzed Hydroarylation of Alkenes with Dialkylanilines.. J. Am. Chem. Soc.. 136, 13594–13597.

Dahcheh, F., Martin D., Stephan D. W., & Bertrand G.. (2014). Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes.. Angew. Chemie, Int. Ed.. 53, 13159–13163.

Martin, D., Lassauque N., Steinmann F., Manuel G., & Bertrand G.. (2013). Experimental and Computational Studies of Anti-Bredt Amidinium Salts.. Chem. - A Eur. J.. 19, 14895–14901.

Mahoney, J. K., Martin D., Moore C. E., Rheingold A. L., & Bertrand G.. (2013). Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes.. J. Am. Chem. Soc.. 135, 18766–18769.

Back, O., Henry-Ellinger M., Martin C. D., Martin D., & Bertrand G.. (2013). 31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the $π$-Accepting Properties of Carbenes.. Angew. Chemie, Int. Ed.. 52, 2939–2943.

Lopez-Gomez, M. J., Martin D., & Bertrand G.. (2013). Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine.. Chem. Commun. (Cambridge, United Kingdom). 49, 4483–4485.

Martin, D., Moore C. E., Rheingold A. L., & Bertrand G.. (2013). An Air-Stable Oxyallyl Radical Cation.. Angew. Chemie, Int. Ed.. 52, 7014–7017.

Martin, D., Lassauque N., Donnadieu B., & Bertrand G.. (2012). A Cyclic Diaminocarbene with a Pyramidalized Nitrogen Atom: A Stable N-Heterocyclic Carbene with Enhanced Electrophilicity.. Angew. Chemie, Int. Ed.. 51, 6172–6175, S6172/1–S6172/19.

Martin, D., Moraleda D., Achard T., Giordano L., & Buono G.. (2011). Assessment of the Electronic Properties of P ligands Stemming from Secondary Phosphine Oxides.. Chem. - A Eur. J.. 17, 12729–12740, S12729/1–S12729/56.

Martin, D., Soleilhavoup M., & Bertrand G.. (2011). Stable singlet carbenes as mimics for transition metal centers.. Chem. Sci.. 2, 389–399.

Martin, D., Melaimi M., Soleilhavoup M., & Bertrand G.. (2011). A Brief Survey of Our Contribution to Stable Carbene Chemistry.. Organometallics. 30, 5304–5313.

Kehrli, S., Martin D., Rix D., Mauduit M., & Alexakis A.. (2010). Formation of Quaternary Chiral Centers by N-Heterocyclic Carbene-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Trisubstituted Cyclic Enones.. Chem. - A Eur. J.. 16, 9890–9904, S9890/1–S9890/104.

Toselli, N., Martin D., Achard M., Tenaglia A., & Buono G.. (2009). Highly Regio- and Stereocontrolled Formation of Functionalized Tricyclo[4.2.1.02,8]non-3-enes.. J. Org. Chem.. 74, 3783–3791.

Toselli, N., Martin D., & Buono G.. (2008). Looking for a Synergic Effect between NHCs and Chiral P-Ligands.. Org. Lett.. 10, 1453–1456.

Toselli, N., Martin D., Achard M., Tenaglia A., Burgi T., & Buono G.. (2008). Enantioselective cobalt-catalyzed [6+2] cycloadditions of cycloheptatriene with alkynes.. Adv. Synth. Catal.. 350, 280–286.

Moraleda, D., Gatineau D., Martin D., Giordano L., & Buono G.. (2008). A simple route to chiral phosphinous acid-boranes.. Chem. Commun. (Cambridge, United Kingdom). 3031–3033.

Alexakis, A., Vuagnoux-d'Augustin M., Martin D., Kehrli S., Palais L., Henon H., et al. (2008). Formation of all-carbon quaternary centers by copper-catalyzed asymmetric conjugate addition.. Chimia (Aarau).. 62, 461–464.

Masuda, J. D., Martin D., Lyon-Saunier C., Baceiredo A., Gornitzka H., Donnadieu B., et al. (2007). Stable P-heterocyclic carbenes: scope and limitations.. Chem. - An Asian J.. 2, 178–187.

Martin, D., Kehrli S., D'Augustin M., Clavier H., Mauduit M., & Alexakis A.. (2006). Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents to Trisubstituted Enones. Construction of All-Carbon Quaternary Chiral Centers.. J. Am. Chem. Soc.. 128, 8416–8417.

Conejero, S., Song M., Martin D., Canac Y., Soleilhavoup M., & Bertrand G.. (2006). New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines.. Chem. - An Asian J.. 1, 155–160.

Martin, D., Tham F. S., Baceiredo A., & Bertrand G.. (2006). Synthesis of extended polyphosphacumulenes.. Chem. - A Eur. J.. 12, 8444–8450.

Martin, D., Baceiredo A., Gornitzka H., Schoeller W. W., & Bertrand G.. (2005). A stable P-heterocyclic carbene.. Angew. Chemie, Int. Ed.. 44, 1700–1703.

Martin, D., Illa O., Baceiredo A., Bertrand G., Ortuno R. M., & Branchadell V.. (2005). Theoretical and experimental investigation of the basicity of phosphino(silyl)carbenes.. J. Org. Chem.. 70, 5671–5677.

Martin, D., Gornitzka H., Baceiredo A., & Bertrand G.. (2005). C-phosphoniophosphaalkenes as precursors of 1$\sigma$4,3$\sigma$2-diphosphaallenes: Scope and limitations.. Eur. J. Inorg. Chem.. 2619–2624.

Martin, D., Baceiredo A., & Bertrand G.. (2004). Synthesis of a persistent 1$\sigma$3,3$\sigma$3-diphosphaallyl cation featuring a localized phosphorus-carbon double bond.. Eur. J. Inorg. Chem.. 3533–3537.

Avarvari, N., Martin D., & Fourmigue M.. (2002). Structural and electrochemical study of metal carbonyl complexes with chelating bis- and tetrakis(diphenylphosphino)tetrathiafulvalenes.. J. Organomet. Chem.. 643-644, 292–300.

2006 - present: CNRS researcher

2015 - present: UMR 5250, Departement of Molecular Chemistry (University of Grenoble-Alpes, Fr)
2010-2014: UMI3555, CNRS-UCSD joint lab, (University of California, USA)
2006-2009: UMR Department of Chirosciences, (University of Marseille, Fr)

2005 - 2006: post-doctoral assistant

Team of Pr A. Alexakis (University of Geneva, Switzerland)

2001 - 2004: PhD

Team of A. Baceiredo (Paul Sabatier University, Toulouse, Fr)

1997 - 2000: Ecole Normale Supérieure (Lyon)

1997 - 2000: Preparatory classes (Lycée Blaise-Pascal, Clermont-Ferrand)

Misc.
   "assistant" fellowship at U. Geneva
   "élève normalien" fellowship at ENS Lyon
   professorship "agrégation de chimie", awarded in 2000

CONTACT

Bâtiment : Chimie C

Bureau : 232

0476514514

David.Martin@univ-grenoble-alpes.fr

Site web :

TRAVAUX MAJEURS

An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents.

An Air-Stable Oxyallyl Radical Cation.

Stable Di‐ and Tri‐coordinated Carbon(II) Supported by an Electron‐Rich β‐Diketiminate Ligand

The quest for observation and isolation of oxyallyl derivatives.

What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis?.

Département de chimie moléculaire

Formulaire de recherche

Annuaire