Ynol Ethers from Dichloroenol Ethers: Mechanistic Elucidation Through 35Cl Labeling.
The mechanism of ynol ether formation from dichloroenol ethers, a decades-old transformation, has been studied by exptl. and theor. techniques to det. the relative importance of the Fritsch-Buttenberg-Wiechell rearrangement ($\alpha$-elimination) and $\beta$-elimination in the evolution of the intermediate carbenoid. [on SciFinder(R)]
Références
- Titre
- Ynol Ethers from Dichloroenol Ethers: Mechanistic Elucidation Through 35Cl Labeling.
- Type de publication
- Article de revue
- Année de publication
- 2008
- Auteurs
- Darses, Benjamin, Milet Anne, Philouze Christian, Greene Andrew E., and Poisson Jean-François
- Revue
- Org. Lett.
- Volume
- 10
- Pagination
- 4445–4447
- ISSN
- 1523-7060
Soumis le 12 avril 2018