Unsymmetrical one-electron oxidized Ni(II)-bis(salicylidene) complexes: a protonation-induced shift of the oxidation site.
The spin d. in the Ni(II) radical salen complex of I (2·)+ could be localized on a specific ring by controlling the acidity of the medium. Protonation of the N,N-dimethylamino induces a significant spin redistribution: the radical of (2·)+ is specifically distributed on the 4-N,N-dimethylamino-2-tert-butylphenoxyl moiety. [on SciFinder(R)]
Références
- Titre
- Unsymmetrical one-electron oxidized Ni(II)-bis(salicylidene) complexes: a protonation-induced shift of the oxidation site.
- Type de publication
- Article de revue
- Année de publication
- 2010
- Auteurs
- Kochem, Amélie, Orio Maylis, Jarjayes Olivier, Neese Frank, and Thomas Fabrice
- Revue
- Chem. Commun. (Cambridge, United Kingdom)
- Volume
- 46
- Pagination
- 6765–6767
- ISSN
- 1359-7345
Soumis le 12 avril 2018