Unprecedented base-promoted nucleophilic addition of diazoesters to nitrones.

A novel and efficient nucleophilic addn. of metalated alpha-diazoacetates to a variety of nitrones is described. This approach provides a series of stable unprecedented beta-[alpha-(hydroxylamino)alkyl]-alpha-diazo esters with great synthetic potential.

Références

Titre
Unprecedented base-promoted nucleophilic addition of diazoesters to nitrones.
Type de publication
Article de revue
Année de publication
2013
Revue
Tetrahedron Lett.
Volume
54
Pagination
5103–5105
ISSN
0040-4039
Soumis le 12 avril 2018