Ultrafast charge transfer excited state dynamics in trifluoromethyl-substituted iridium(III) complexes.

Time-resolved spectroscopy was exploited to gain new insights into the nature and dynamics of charge transfer excited states of bis-cyclometalated Ir(III) complexes. Its dynamics is strongly influenced by the nature of the diimine ligand due to the existence of a ligand-ligand charge transfer process in the picosecond timescale. All the results are supported by DFT/TD-DFT calcns. and spectroelectrochem. [on SciFinder(R)]

Références

Titre
Ultrafast charge transfer excited state dynamics in trifluoromethyl-substituted iridium(III) complexes.
Type de publication
Article de revue
Année de publication
2018
Revue
Phys. Chem. Chem. Phys.
Volume
20
Pagination
27256–27260
ISSN
1463-9076
Soumis le 21 février 2019