Ultrafast charge transfer excited state dynamics in trifluoromethyl-substituted iridium(III) complexes.
Time-resolved spectroscopy was exploited to gain new insights into the nature and dynamics of charge transfer excited states of bis-cyclometalated Ir(III) complexes. Its dynamics is strongly influenced by the nature of the diimine ligand due to the existence of a ligand-ligand charge transfer process in the picosecond timescale. All the results are supported by DFT/TD-DFT calcns. and spectroelectrochem. [on SciFinder(R)]
Références
- Titre
- Ultrafast charge transfer excited state dynamics in trifluoromethyl-substituted iridium(III) complexes.
- Type de publication
- Article de revue
- Année de publication
- 2018
- Auteurs
- Bevernaegie, Robin, Marcelis Lionel, Moreno-Betancourt Angélica, Laramee-Milette Baptiste, Hanan Garry S., Loiseau Frédérique, Sliwa Michel, and Elias Benjamin.
- Revue
- Phys. Chem. Chem. Phys.
- Volume
- 20
- Pagination
- 27256–27260
- ISSN
- 1463-9076
Soumis le 21 février 2019