Tuning the redox potential of vitamin K3 derivatives by oxidative functionalization using a Ag(I)/GO catalyst.

We propose herein initial results to develop optimum redox mediators by the combination of computational simulation and catalytic functionalization of the core structure of vitamin K3. We aim to correlate the calcd. energy value of the LUMO of different vitamin K3 derivs. with their actual redox potential. For this, we optimized the catalytic alkylation of 1,4-naphthoquinones with a designed Ag(I)/GO catalyst and synthesized a series of mols. [on SciFinder(R)]

Références

Titre
Tuning the redox potential of vitamin K3 derivatives by oxidative functionalization using a Ag(I)/GO catalyst.
Type de publication
Article de revue
Année de publication
2017
Revue
Chem. Commun. (Cambridge, United Kingdom)
Volume
53
Pagination
8890–8893
ISSN
1359-7345
Soumis le 12 avril 2018