Thiophenol

Abstract [109-98-5] C6H6S (MW 110.19) InChI = 1S/C6H6S/c7-6-4-2-1-3-5-6/h1-5,7H InChIKey = RMVRSNDYEFQCLF-UHFFFAOYSA-N (precursor of the thiophenoxy radical, which adds to alkenes and alkynes, initiating cyclizations; cis/trans alkene isomerization; synthesis of vinyl sulfides, alkyllithiums, pyridines; transacetalization; Michael addition) Physical Data: mp −15 °C; bp 169 °C, 46.4 °C/4 mmHg; n20 1.5893; d20 1.0766 g cm−3. Solubility: sol alcohol, ether, benzene, methylene chloride. Form Supplied in: liquid; commercially available. Handling, Storage, and Precautions: handle under an inert atmosphere as oxygen causes oxidation to the disulfide. This may accelerated in the presence of base. Stench reminiscent of garlic. Very toxic. Handle only in an efficient fume hood.

Références

Titre
Thiophenol
Type de publication
Book Chapter
Année de publication
2006
Book Title
Encyclopedia of Reagents for Organic Synthesis
Éditeur
American Cancer Society
ISBN
9780470842898
Soumis le 2 juillet 2019