Tandem SmI2-induced nitrone $\beta$-elimination/aldol-type reaction.

Upon treatment with SmI2, the carbohydrate-derived nitrones undergo a $\beta$-elimination of the benzyloxy group at C-1, forming original samarium(III) oxy-enamine intermediates. The latter can be reacted with carbonyl compds. to produce aldol-type adducts. The tandem process results in the transformation of a C-O bond into a C-C bond. [on SciFinder(R)]

Références

Titre
Tandem SmI2-induced nitrone $\beta$-elimination/aldol-type reaction.
Type de publication
Article de revue
Année de publication
2009
Revue
Org. Biomol. Chem.
Volume
7
Pagination
3385–3387
ISSN
1477-0520
Soumis le 12 avril 2018