Tandem catalytic C(sp3)-H amination/sila-Sonogashira-Hagihara coupling reactions with iodine reagents
A new tandem C-N and C-C bond-forming reaction has been achieved through Rh(II) /Pd(0) catalysis. The sequence first involves an iodine(III) oxidant, then the in situ generated iodine(I) by-product is used as a coupling partner. The overall process demonstrates the synthetic value of iodoarenes produced in trivalent iodine reagent mediated oxidations.
Références
- Titre
- Tandem catalytic C(sp3)-H amination/sila-Sonogashira-Hagihara coupling reactions with iodine reagents
- Type de publication
- Article de revue
- Année de publication
- 2015
- Auteurs
- Buendia, Julien, Darses Benjamin, and Dauban Philippe
- Revue
- Angewandte Chemie - International Edition
- Volume
- 54
- Pagination
- 5697–5701
- ISSN
- 15213773
- ISBN
- 1521-3773
Soumis le 25 septembre 2018