Synthesis, spectroscopic, cyclic voltammetry properties and molecular structure of the thiocyanato-N meso-tetratolylporphyrinato zinc(II) ion complex.
{This paper describes the synthesis of the (thiocyanato-N)(meso-tetratolylporphyrinato)zinc(II) chlorobenzene monosolvate complex with the formula [K(2,2,2-crypt)][Zn(TTP)(NCS)]·C6H5Cl (1) using the cryptand-222 to solubilize potassium thiocyanate in chlorobenzene solvent. Complex (1) has been characterized by elemental anal., IR, UV-visible, 1H NMR and MS, and the structure of this new zinc(II) metalloporphyrin been examd. crystallog. A cyclic voltammetry investigation was also carried out on this species. The title compd. crystallizes in the triclinic, space group P-1, with a 11.5151(7), b 15.212(10), c 20.1093(12) {\AA}, $\alpha$ 80.428(4), $\beta$ 74.926(4), $\gamma$ 84.704(4)°
Références
- Titre
- Synthesis, spectroscopic, cyclic voltammetry properties and molecular structure of the thiocyanato-N meso-tetratolylporphyrinato zinc(II) ion complex.
- Type de publication
- Article de revue
- Année de publication
- 2017
- Auteurs
- Denden, Zouhour, Harhouri Wafa, Hassen Leila Ben Haj, Rousselin Yoann, Saint-Aman Eric, and Nasri Habib.
- Revue
- J. Mol. Struct.
- Volume
- 1133
- Pagination
- 472–478
- ISSN
- 0022-2860
Soumis le 12 avril 2018