Synthesis of 3,6-dimethoxybenzene-1,2-diamine and of 4,7-dimethoxy-2-methyl-1H-benzimidazole.

Hydrogenation of a mixt. of ortho- and para-dinitro derivs. of 1,4-dimethoxybenzene in Et acetate under palladium catalysis yields 3,6-dimethoxybenzene-1,2-diamine as the sole product. This diamine is then converted into 4,7-dimethoxy-2-methyl-1H-benzimidazole, a building block for the prepn. of imidazobenzo(hydro)quinones. [on SciFinder(R)]

Références

Titre
Synthesis of 3,6-dimethoxybenzene-1,2-diamine and of 4,7-dimethoxy-2-methyl-1H-benzimidazole.
Type de publication
Article de revue
Année de publication
2009
Revue
Synthesis (Stuttg).
Pagination
1753–1756
ISSN
0039-7881
Soumis le 12 avril 2018