Synthesis of 3,6-dimethoxybenzene-1,2-diamine and of 4,7-dimethoxy-2-methyl-1H-benzimidazole.
Hydrogenation of a mixt. of ortho- and para-dinitro derivs. of 1,4-dimethoxybenzene in Et acetate under palladium catalysis yields 3,6-dimethoxybenzene-1,2-diamine as the sole product. This diamine is then converted into 4,7-dimethoxy-2-methyl-1H-benzimidazole, a building block for the prepn. of imidazobenzo(hydro)quinones. [on SciFinder(R)]
Références
- Titre
- Synthesis of 3,6-dimethoxybenzene-1,2-diamine and of 4,7-dimethoxy-2-methyl-1H-benzimidazole.
- Type de publication
- Article de revue
- Année de publication
- 2009
- Auteurs
- Besset, Tatiana, and Morin Christophe.
- Revue
- Synthesis (Stuttg).
- Pagination
- 1753–1756
- ISSN
- 0039-7881
Soumis le 12 avril 2018