A Structurally Characterized CuIII Complex Supported by a Bis(anilido) Ligand and Its Oxidative Catalytic Activity.

Three Cu(II) complexes of the (R,R)-N,N'-bis(3,5-di-tert-butyl-2-aminobenzylidene)-1,2-diaminocyclohexane ligand, [Cu(NL)], [Cu(NLH)]+ and [Cu(NLH2)]2+, were prepd. and structurally characterized. In [Cu(NLH2)]2+ the Cu ion lies in an octahedral geometry with the aniline groups coordinated in equatorial positions. In [Cu(NL)] the anilines are deprotonated (anilido moieties) and coordinated to an almost square-planar metal ion. [Cu(NL)] displays two oxidn. waves at E1/2ox.

Références

Titre
A Structurally Characterized CuIII Complex Supported by a Bis(anilido) Ligand and Its Oxidative Catalytic Activity.
Type de publication
Article de revue
Année de publication
2017
Revue
Chem. Eur. J.
Volume
23
Pagination
13929–13940
ISSN
0947-6539
Soumis le 12 avril 2018