Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex - the reactivity toward S-alkylation: an experimental and theoretical study.
{The structural, spectroscopic, redox properties and also the reactivity toward S-alkylation of a new mononuclear N2S2 dithiolate CoII complex [CoL] (1), with H2L = 2,2'-(2,2'-bipyridine-6,6'-diyl)bis(1,1-diphenylethanethiol), were investigated. The x-ray structure of 1 revealed an unusual distorted square planar geometry for a CoII ion within a thiolate environment. The X-band EPR spectrum of 1 displays a rhombic S = 1/2 signal consistent with a low spin configuration for the d7 CoII ion with a large g-anisotropy (gx = 2.94
Références
- Titre
- Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex - the reactivity toward S-alkylation: an experimental and theoretical study.
- Type de publication
- Article de revue
- Année de publication
- 2012
- Auteurs
- Gennari, Marcello, Gerey Bertrand, Hall Nikita, Pécaut Jacques, Vezin Hervé, Collomb Marie-Noelle, Orio Maylis, and Duboc Carole
- Revue
- Dalt. Trans.
- Volume
- 41
- Pagination
- 12586–12594
- ISSN
- 1477-9226
Soumis le 12 avril 2018