Structural snapshots of the rearrangement of the bis(di-tert-butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions
The bis(di-tert-butyl-aminophenyl)amine ligand H3LN{,}N{,}N was reacted with Mn(ii){,} Co(ii){,} Fe(iii) and Cu(ii) salts in air. The ligand undergoes oxidative transformations{,} which involve intra and intermolecular CâN and NâN bond formations. A rare aromatic CâN bond cleavage leading to a CâO bond has also been observed.
Références
- Titre
- Structural snapshots of the rearrangement of the bis(di-tert-butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions
- Type de publication
- Article de revue
- Année de publication
- 2018
- Auteurs
- Leconte, Nicolas, Baptiste B., Philouze Christian, and Thomas Fabrice
- Revue
- Dalton Trans.
- Volume
- 47
- Pagination
- 11303-11307
Soumis le 28 août 2018