Stereocontrolled Total Synthesis of (+)-1-Deoxynojirimycin.

A highly efficient non-chiral-pool synthesis of (+)-1-deoxynojirimycin has been realized (24 {%} overall yield, 11 steps, complete stereocontrol). A novel one-pot enol ether metathesis/hydroboration/oxidn. sequence is used for the selective formation of the all-trans cyclic triol. © Wiley-VCH Verlag GmbH {&} Co. KGaA, 69451 Weinheim, Germany, 2009. [on SciFinder(R)]

Références

Titre
Stereocontrolled Total Synthesis of (+)-1-Deoxynojirimycin.
Type de publication
Article de revue
Année de publication
2009
Revue
European J. Org. Chem.
Pagination
4221–4224, S4221/1–S4221/11
ISSN
1434-193X
Soumis le 12 avril 2018