Spanning Pairs of Rh2(acetate)4 Units with Ru(II) Complexes.
A synthetic route to linear pairs of Rh2 triacetate paddlewheel dimers bridged by Ru(II) complexes is presented. A bis(4'-(4-carboxyphenyl)-terpyridine)Ru(II) complex spans two Rh2 dimers and displays a 26. {\AA} sepn. between the dimers. Increased electronic interaction is found for the dimer of dimers without the Ph groups using bis(4'-(4-carboxy)-terpyridine)Ru(II) as the bridging complex. [on SciFinder(R)]
Références
- Titre
- Spanning Pairs of Rh2(acetate)4 Units with Ru(II) Complexes.
- Type de publication
- Article de revue
- Année de publication
- 2008
- Auteurs
- Cooke, Michael W., Santoni Marie-Pierre, Hanan Garry S., Loiseau Frédérique, Proust Anna, and Hasenknopf Bernold.
- Revue
- Inorg. Chem.
- Volume
- 47
- Pagination
- 6112–6114
- ISSN
- 0020-1669
Soumis le 12 avril 2018