Solid-State Electrochemistry and Electrochemiluminescence of Porous Thin Film of [(2,2'-Bipyridyl)(4-(2-pyrrol-1-ylethyl)-4'-methyl-2,2'-bipyridyl)2]ruthenium(II) Monomer Precipitation.
A novel fluorescent porous thin film based on the pptn. of the [(2,2'-bipyridyl)(4-(2-pyrrol-1-ylethyl)-4'-methyl-2,2'-bipyridyl)2]ruthenium(II) (BF4)2 complex (pyr-Ru) was fabricated by easily spreading 2 $μ$L of pyr-Ru (1 mM in MeCN soln.) onto the surface of a Pt electrode and drying it in ambient conditions. The morphol. of the resulting pyr-Ru thin film was characterized by SEM and fluorescence microscopy. The coating exhibits fluorescent properties of the Ru complex and a porous structure with pore diams. of micrometers. The solid-state electrochem. and electrochemiluminescence behaviors of the porous pyr-Ru thin film were studied in aq. soln. by cyclic voltammetry and step potential. [on SciFinder(R)]
Références
- Titre
- Solid-State Electrochemistry and Electrochemiluminescence of Porous Thin Film of [(2,2'-Bipyridyl)(4-(2-pyrrol-1-ylethyl)-4'-methyl-2,2'-bipyridyl)2]ruthenium(II) Monomer Precipitation.
- Type de publication
- Article de revue
- Année de publication
- 2011
- Auteurs
- Ding, Shou-Nian, Zhu Wei, Shan Dan, Wan Neng, Sun Yue-Ming, and Cosnier Serge
- Revue
- Electroanalysis
- Volume
- 23
- Pagination
- 1306–1310
- ISSN
- 1040-0397
Soumis le 12 avril 2018