Single-Laser-Shot-Induced Complete Bidirectional Spin Transition at Room Temperature in Single Crystals of (FeII(pyrazine)(Pt(CN)4))
Single crystals of the {\{}FeII(pyrazine)[Pt(CN)4]{\}} spin crossover complex were synthesized by a slow diffusion method. The crystals exhibit a thermal spin transition around room temperature (298 K), which is accompanied by a 14 K wide hysteresis loop. X-ray single-crystal anal. confirms that this compound crystallizes in the tetragonal P4/mmm space group in both spin states. Within the thermal hysteresis region a complete bidirectional photoconversion was induced between the two phases (high spin ⇄ low spin) when a short single laser pulse (4 ns, 532 nm) was shined on the sample.
Références
- Titre
- Single-Laser-Shot-Induced Complete Bidirectional Spin Transition at Room Temperature in Single Crystals of (FeII(pyrazine)(Pt(CN)4))
- Type de publication
- Article de revue
- Année de publication
- 2008
- Auteurs
- Cobo, Saioa, Ostrovskii Denis, Bonhommeau Sebastien, Vendier Laure, Molnar Gabor, Salmon Lionel, Tanaka Koichiro, and Bousseksou Azzedine
- Revue
- J. Am. Chem. Soc.
- Volume
- 130
- Pagination
- 9019–9024
- ISSN
- 0002-7863
Soumis le 26 juin 2018