Self-assembled dimethyldihydropyrene-pyridyl substituted ligands with zinc(II) meso-tetraphenylporphyrin via axial coordination

A series of dimethyldihydropyrene (DHP)-pyridyl photochromic derivatives has been synthesized and its photochem. behavior characterized by spectroscopic and electrochem. methods. The corresponding noncovalently-linked electron donor-acceptor complexes have been isolated. They combine the DHP-pyridyl ligand as a donor and the zinc(II) tetraphenylporphyrin as acceptor. Such association allowed to explore the efficiency of dative bonds to monitor the interactions between the two units.

Références

Titre
Self-assembled dimethyldihydropyrene-pyridyl substituted ligands with zinc(II) meso-tetraphenylporphyrin via axial coordination
Type de publication
Article de revue
Année de publication
2016
Revue
Dalt. Trans.
Volume
45
Pagination
16453–16462
ISSN
1477-9226
Soumis le 26 juin 2018