In search for thioketene S-oxide. A vinyl sulfoxide to sulfine rearrangement

Two approaches to thioketene S-oxide have been tested. This reactive heterocumulene was tentatively characterized by low temperature IR spectroscopy. In the course of this study, an unexpected vinyl sulfoxide to sulfine rearrangement was observed.

Références

Titre
In search for thioketene S-oxide. A vinyl sulfoxide to sulfine rearrangement
Type de publication
Article de revue
Année de publication
1998
Revue
Tetrahedron Letters
Volume
39
Ticket
27
Pagination
4813–4816
ISSN
0040-4039
Soumis le 2 juillet 2019