Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(I) complexes.
The room temp. hydroamination of alkynes with phenylhydrazine and anilines was achieved with an anti-Bredt di(amino) carbene gold(I) chloride as precatalyst, in the presence of KBArF as chloride scavenger. These reactions were highly regioselective and excellent conversions were obtained (up to 99{%}) for a series of alkynes and anilines. [on SciFinder(R)]
Références
- Titre
- Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(I) complexes.
- Type de publication
- Article de revue
- Année de publication
- 2016
- Auteurs
- Hu, Xingbang, Martin David, and Bertrand Guy.
- Revue
- New J. Chem.
- Volume
- 40
- Pagination
- 5993–5996
- ISSN
- 1144-0546
Soumis le 12 avril 2018