Phenols and Tertiary Amines: An Amazingly Simple Hydrogen-Bonding Organocatalytic System Promoting Ring Opening Polymerization.
A simple and easily available organocatalytic system was developed for the polymn. of lactide. In partnership with tertiary amines, phenol derivs. were demonstrated to be excellent single H-bonding catalysts with high conversion within 24 h. In particular, ortho-, meta- and meta,meta'-trifluoromethylphenols revealed an amazing capacity for triggering the controlled ring opening polymn. (ROP) of lactide, through a fitted hydrogen-bond with the monomer. [on SciFinder(R)]
Références
- Titre
- Phenols and Tertiary Amines: An Amazingly Simple Hydrogen-Bonding Organocatalytic System Promoting Ring Opening Polymerization.
- Type de publication
- Article de revue
- Année de publication
- 2011
- Auteurs
- Thomas, Coralie, Peruch Frederic, Deffieux Alain, Milet Anne, Desvergne Jean-Pierre, and Bibal Brigitte.
- Revue
- Adv. Synth. Catal.
- Volume
- 353
- Pagination
- 1049–1054
- ISSN
- 1615-4150
Soumis le 12 avril 2018