Phenols and Tertiary Amines: An Amazingly Simple Hydrogen-Bonding Organocatalytic System Promoting Ring Opening Polymerization.

A simple and easily available organocatalytic system was developed for the polymn. of lactide. In partnership with tertiary amines, phenol derivs. were demonstrated to be excellent single H-bonding catalysts with high conversion within 24 h. In particular, ortho-, meta- and meta,meta'-trifluoromethylphenols revealed an amazing capacity for triggering the controlled ring opening polymn. (ROP) of lactide, through a fitted hydrogen-bond with the monomer. [on SciFinder(R)]

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Titre
Phenols and Tertiary Amines: An Amazingly Simple Hydrogen-Bonding Organocatalytic System Promoting Ring Opening Polymerization.
Type de publication
Article de revue
Année de publication
2011
Revue
Adv. Synth. Catal.
Volume
353
Pagination
1049–1054
ISSN
1615-4150
Soumis le 12 avril 2018