Oxidative perhydroxylation of [closo-B12H12]2- to the stable inorganic cluster redox system [B12(OH)12]2-/·-: experiment and theory.
A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12]2- not only to [closo-B12(OH)12]2- but also, at less-elevated temps., to the new [hypocloso-B12(OH)12]·- radical anion. Both approx. icosahedral closo and hypocloso cluster ions were structurally characterized as the Cs salts and their properties were assessed exptl. and theor. [on SciFinder(R)]
Références
- Titre
- Oxidative perhydroxylation of [closo-B12H12]2- to the stable inorganic cluster redox system [B12(OH)12]2-/·-: experiment and theory.
- Type de publication
- Article de revue
- Année de publication
- 2010
- Auteurs
- Nguyen, Van, Tiritiris Ioannis, Winter Rainer F., Sarkar Biprajit, Singh Priti, Duboc Carole, Muñoz-Castro Alvaro, Arratia-Pérez Ramiro, Kaim Wolfgang, and Schleid Thomas.
- Revue
- Chem. - A Eur. J.
- Volume
- 16
- Pagination
- 11242–11245, S11242/1–S11242/8
- ISSN
- 0947-6539
Soumis le 12 avril 2018