Origin of the Zero-Field Splitting in Mononuclear Octahedral Dihalide MnII Complexes: An Investigation by Multifrequency High-Field Electron Paramagnetic Resonance and Density Functional Theory.
{The synthesis, structural characterization, and electronic properties of high-spin six-coordinate dihalide mononuclear MnII complexes [Mn(tpa)X2] (tpa = tris-2-picolylamine; X = I (1), Br (2), and Cl (3)) are reported. The anal. of the crystallog. data shows that in all studied complexes the manganese ion lies in the center of a distorted octahedron with a cis configuration of the halides imposed by the tpa ligand. By a multifrequency high-field ESR study (95-285 GHz), the electronic properties of 1-3 were detd. (DI = -0.600
Références
- Titre
- Origin of the Zero-Field Splitting in Mononuclear Octahedral Dihalide MnII Complexes: An Investigation by Multifrequency High-Field Electron Paramagnetic Resonance and Density Functional Theory.
- Type de publication
- Article de revue
- Année de publication
- 2007
- Auteurs
- Duboc, Carole, Phoeung Thida, Zein Samir, Pécaut Jacques, Collomb Marie-Noelle, and Neese Frank
- Revue
- Inorg. Chem.
- Volume
- 46
- Pagination
- 4905–4916
- ISSN
- 0020-1669
Soumis le 12 avril 2018