Organocatalyst-mediated enantioselective intramolecular Michael addition of aldehydes to vinyl sulfones

Chiral amines with a hydrogen bond donor promote the intramolecular conjugate addition of aldehydes to vinyl sulfones. Chiral cyclic sulfone-aldehydes are obtained in good yields with an ee of up to 82%.

Références

Titre
Organocatalyst-mediated enantioselective intramolecular Michael addition of aldehydes to vinyl sulfones
Type de publication
Article de revue
Année de publication
2010
Revue
Tetrahedron: Asymmetry
Volume
21
Ticket
13
Pagination
1666–1673
ISSN
0957-4166
Soumis le 7 septembre 2022