An Odd-Electron Complex [Ruk(NOm)(Qn)(terpy)]2+ with Two Prototypical Non-Innocent Ligands.
{Six combinations of oxidn. states are conceivable for the paramagnetic [Ruk(NOm)(Qn)(terpy)]2+ complex. Single-crystal X-ray diffraction, spectroscopic anal. (IR, EPR at conventional and high frequency), and DFT calcns. establish that it is the iminosemiquinone radical structure that is formed: [Ruk(NOm)(Qn)(terpy)]2+ (k=2+
Références
- Titre
- An Odd-Electron Complex [Ruk(NOm)(Qn)(terpy)]2+ with Two Prototypical Non-Innocent Ligands.
- Type de publication
- Article de revue
- Année de publication
- 2009
- Auteurs
- Das, Atanu Kumar, Sarkar Biprajit, Duboc Carole, Strobel Sabine, Fiedler Jan, Zális Stanislav, Lahiri Goutam Kumar, and Kaim Wolfgang.
- Revue
- Angew. Chemie, Int. Ed.
- Volume
- 48
- Pagination
- 4242–4245, S4242/1–S4242/6
- ISSN
- 1433-7851
- Mots-clés
- crystal structure ruthenium nitrosyl terpyridine iminobenzoquinone complex cyclic voltammetry ruthenium nitrosyl terpyridine iminobenzoquinone complex electronic structure ruthenium nitrosyl terpyridine iminobenzoquinone complex optimized geometry ruthenium nitrosyl terpyridine iminobenzoquinone isomeric complex ruthenium nitrosyl terpyridine iminobenzoquinone complex prepn structure
Soumis le 12 avril 2018