Non-heme iron hydroperoxo species in superoxide reductase as a catalyst for oxidation reactions.
The non-heme high-spin ferric iron hydroperoxo species formed in superoxide reductase catalyzes oxidative aldehyde deformylation through its nucleophilic character. This species also acts as an electrophile to catalyze oxygen atom transfer in sulfoxidn. reactions, highlighting the oxidn. potential of non-heme iron hydroperoxo species. [on SciFinder(R)]
Références
- Titre
- Non-heme iron hydroperoxo species in superoxide reductase as a catalyst for oxidation reactions.
- Type de publication
- Article de revue
- Année de publication
- 2014
- Auteurs
- Rat, S, Menage Stephane., Thomas Fabrice, and Niviere V
- Revue
- Chem. Commun. (Cambridge, United Kingdom)
- Volume
- 50
- Pagination
- 14213–14216
- ISSN
- 1359-7345
Soumis le 12 avril 2018