Ni(II) Complexes of the Redox-Active Bis(2-aminophenyl)dipyrrin: Structural, Spectroscopic, and Theoretical Characterization of Three Members of an Electron Transfer Series.
{The sterically hindered bis(2-aminophenyl)dipyrrin ligand H3NL was prepd. X-ray diffraction discloses a bifurcated hydrogen bonding network involving the dipyrrin and one aniline ring. The reaction of H3NL with one equiv. of nickel(II) in the air produces a paramagnetic neutral complex, which absorbs intensively in the visible-NIR region. Its ESR spectrum displays resonances at g1 = 2.033
Références
- Titre
- Ni(II) Complexes of the Redox-Active Bis(2-aminophenyl)dipyrrin: Structural, Spectroscopic, and Theoretical Characterization of Three Members of an Electron Transfer Series.
- Type de publication
- Article de revue
- Année de publication
- 2017
- Auteurs
- Moutet, Jules, Philouze Christian, Du Moulinet D'Hardemare Amaury, Leconte Nicolas, and Thomas Fabrice
- Revue
- Inorg. Chem.
- Volume
- 56
- Pagination
- 6380–6392
- ISSN
- 0020-1669
Soumis le 12 avril 2018