Mössbauer Spectroscopic and Computational Investigation of An Iron Cyclopentadienone Complex

(Cyclopentadienone)iron carbonyl complexes have recently received particular attention for their use as catalysts in hydrogenation or transfer hydrogenation reactions including the N-alkylation of amines with alcohols. This is due to their easy synthesis from simple and cheap materials, air and water stabilities, and the crucial metal–ligand cooperation giving rise to unique catalytic properties. Here, we report a Mössbauer spectroscopic and computational investigation of such a complex and its corresponding activated species for dehydrogenation and hydrogenation reactions. This study affords a deeper understanding of the species formed by the reaction with Me3NO and their distribution upon the added amount of an oxidant.

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Titre
Mössbauer Spectroscopic and Computational Investigation of An Iron Cyclopentadienone Complex
Type de publication
Article de revue
Année de publication
2021
Revue
Inorganic Chemistry
Volume
60
Ticket
15
Pagination
11192–11199
ISSN
0020-1669
Soumis le 7 septembre 2022