Mn(IV) and Mn(V)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand.
The electron-rich pincer ligand bis(2-amino-3,5-di-tert-butylphenyl)amine (1) was synthesized and chelated to Mn. The octahedral Mn(IV) bis(diiminosemiquinonate) and Mn(V) (diiminobenzoquinone) (diiminosemiquinonate) radicals were structurally characterized. [on SciFinder(R)]
Références
- Titre
- Mn(IV) and Mn(V)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand.
- Type de publication
- Article de revue
- Année de publication
- 2017
- Auteurs
- Leconte, Nicolas, Moutet Jules, Herasymchuk Khrystyna, Clarke Ryan M., Philouze Christian, Luneau Dominique, Storr Tim, and Thomas Fabrice
- Revue
- Chem. Commun. (Cambridge, United Kingdom)
- Volume
- 53
- Pagination
- 2764–2767
- ISSN
- 1359-7345
Soumis le 12 avril 2018