[Mn(bipyridyl)CO3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction.

An usage of manganese complex and its advantages for carbon dioxide redn. are described in comparison with iridium complexes. The manganese complex allowed for redn. at markedly lower overpotentials (gain of 0.4 V) with selectivity and Faradaic efficiency almost identical. The catalysts could be prepd. by a simple mixing of components. [on SciFinder(R)]

Références

Titre
[Mn(bipyridyl)CO3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction.
Type de publication
Article de revue
Année de publication
2011
Revue
Angew. Chemie, Int. Ed.
Volume
50
Pagination
9903–9906, S9903/1–S9903/9
ISSN
1433-7851
Soumis le 12 avril 2018