MiPNO, a new chiral cyclic nitrone for enantioselective amino acid synthesis: the cycloaddition approach.

The resoln. of chiral nitrones via derivatization of hydroxylamines was applied to MiPNO, a new, stable, easily prepd. chiral cyclic nitrone. The application of MiPNO in totally regio- and diastereo-selective 1,3-dipolar cycloaddn. reactions provides an expeditious enantioselective access to unusual $\gamma$-hydroxy $\alpha$-amino acids. [on SciFinder(R)]

Références

Titre
MiPNO, a new chiral cyclic nitrone for enantioselective amino acid synthesis: the cycloaddition approach.
Type de publication
Article de revue
Année de publication
2010
Revue
Org. Biomol. Chem.
Volume
8
Pagination
864–872
ISSN
1477-0520
Soumis le 12 avril 2018