Mechanistic investigations of the phosphine-mediated nitrone deoxygenation reaction and its application in cyclic imine synthesis.
Carbohydrate-derived cyclic nitrones were deoxygenated to form the corresponding imines using tributylphosphine. Exptl. and theor. investigations by the way of MP2 calcns. suggest a revision of the mechanism initially proposed by Kurtzweil and Beak for the triarylphosphine-mediated deoxygenation of nitrones. [on SciFinder(R)]
Références
- Titre
- Mechanistic investigations of the phosphine-mediated nitrone deoxygenation reaction and its application in cyclic imine synthesis.
- Type de publication
- Article de revue
- Année de publication
- 2009
- Auteurs
- Cividino, Pascale, Dheu-Andries Marie-Louise, Ou Jun, Milet Anne, Py Sandrine, and Toy Patrick H.
- Revue
- Tetrahedron Lett.
- Volume
- 50
- Pagination
- 7038–7042
- ISSN
- 0040-4039
Soumis le 12 avril 2018