Looking for a Synergic Effect between NHCs and Chiral P-Ligands.
The issue of the added value of NHCs in asym. catalysis with respect to trusted chiral P-ligands was addressed: considering a prototypical asym. allylic alkylation reaction as a model, the assocn. of a priori inhibiting and achiral NHCs with modular P-ligand resulted in enhancement of er up to 508{%} and increased rates. [on SciFinder(R)]
Références
- Titre
- Looking for a Synergic Effect between NHCs and Chiral P-Ligands.
- Type de publication
- Article de revue
- Année de publication
- 2008
- Auteurs
- Toselli, Nicolas, Martin David, and Buono Gerard.
- Revue
- Org. Lett.
- Volume
- 10
- Pagination
- 1453–1456
- ISSN
- 1523-7060
Soumis le 21 janvier 2019