Lithium Amide Protected against Hydrolysis by Aggregated Lithium Halides studied by mass spectrometry and DFT.
Supported by mass spectrometry expts., DFT computations indicate that the lithium amide of a 3-aminopyrrolidine (lithium benzhydryl(1-benzylpyrrolidin-3-yl)amide, 1-Li) is protected, up to a certain limit, against hydrolysis when it is aggregated with a strongly polar partner such as LiCl, LiBr, or MeLi.
Références
- Titre
- Lithium Amide Protected against Hydrolysis by Aggregated Lithium Halides studied by mass spectrometry and DFT.
- Type de publication
- Article de revue
- Année de publication
- 2017
- Auteurs
- Gimbert, Yves, Lesage Denis, Fressigne Catherine, and Maddaluno Jacques.
- Revue
- J. Org. Chem.
- Volume
- 82
- Pagination
- 8141–8147
- ISSN
- 0022-3263
Soumis le 12 avril 2018