An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols
Three is a lucky number: An enantioselective transformation of allylic alcohols into beta-chiral saturated alcohols has been developed by combining two distinct metal- and organocatalyzed catalytic cycles. This waste-free triple cascade process merges an iron-catalyzed borrowing-hydrogen step with an aminocatalyzed nucleophilic addition reaction.
Références
- Titre
- An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols
- Type de publication
- Article de revue
- Année de publication
- 2013
- Auteurs
- Quintard, Adrien, Constantieux Thierry, and Rodriguez Jean
- Revue
- Angewandte Chemie International Edition
- Volume
- 52
- Ticket
- 49
- Pagination
- 12883–12887
Soumis le 7 septembre 2022