Highly Diastereoselective and Irreversible Aldol Reactions of N-Sulfonylimidates.
A mild method for the aldolization of N-sulfonylimidates was developed. The reaction proceeded in excellent diastereoselectivity to provide a range of useful beta-hydroxyimidates in high yield. The innate reversibility of the reaction was suppressed by the use of a titanium complex as a Lewis acid.
Références
- Titre
- Highly Diastereoselective and Irreversible Aldol Reactions of N-Sulfonylimidates.
- Type de publication
- Article de revue
- Année de publication
- 2016
- Auteurs
- Bartrum, Hannah E., Carret Sébastien, and Poisson Jean-François
- Revue
- Synthesis
- Volume
- 48
- Pagination
- 3413–3419
- ISSN
- 1437-210X
Soumis le 12 avril 2018