Formation of Polymeric [\Ru0(bpy)(CO)2\}n] Films by Electrochemical Reduction of [Ru(bpy)2(CO)2](PF6)2: Its Implication in CO2 Electrocatalytic Reduction.}
The bi-electron redn. of cis-[Ru(bpy)2(CO)2](PF6)2 leads to the formation of films of polymeric complex [{\{}Ru0(bpy)(CO)2{\}}n] in acetonitrile under argon. Although in CO2-satd. solns., the hydrido [Ru(bpy)2(CO)H]+ complex formation competes with that of the film, the later appears as the main catalyst species for the almost quant. and selective redn. of CO2 to CO. [on SciFinder(R)]
Références
- Titre
- Formation of Polymeric [\Ru0(bpy)(CO)2\}n] Films by Electrochemical Reduction of [Ru(bpy)2(CO)2](PF6)2: Its Implication in CO2 Electrocatalytic Reduction.}
- Type de publication
- Article de revue
- Année de publication
- 1994
- Auteurs
- Chardon, Sylvie, Collomb Marie-Noelle, Deronzier Alain, Ziessel Raymond, and Zsoldos Daniela.
- Revue
- Inorg. Chem.
- Volume
- 33
- Pagination
- 4410–4412
- ISSN
- 0020-1669
Soumis le 15 juin 2018