Fluorescent and redox tetrazine films by host-guest immobilization of tetrazine derivatives within poly(pyrrole-$\beta$-cyclodextrin) films.

Tetrazines were immobilized onto electrogenerated films of polypyrrole functionalized with $\beta$-cyclodextrin. Their immobilization was ascribed to the formation of the inclusion complexes between the tetrazines derivs. and the $\beta$-cyclodextrin cavity. The resulting supramol. material kept the electrochem. and fluorescent properties of tetrazines. This original architecture was used with success as a bridge to immobilize the $\beta$-cyclodextrin-tagged glucose oxidase, chosen as an enzyme model, to prove the efficiency of the method to build new supra-biomol. architectures. [on SciFinder(R)]

Références

Titre
Fluorescent and redox tetrazine films by host-guest immobilization of tetrazine derivatives within poly(pyrrole-$\beta$-cyclodextrin) films.
Type de publication
Article de revue
Année de publication
2016
Revue
J. Electroanal. Chem.
Volume
781
Pagination
36–40
ISSN
1873-2569
Soumis le 12 avril 2018