Ferrocyanide-Ferricyanide Redox Couple Induced Electrochemiluminescence Amplification of Carbon Dots for Ultrasensitive Sensing of Glutathione.
Here the authors report a novel solid-state ECL sensor for ultrasensitive sensing of glutathione (GSH) based on ferrocyanide-ferricyanide redox couple (Fe(CN)63-/4-) induced electrochemiluminescence (ECL) amplification of carbon dots (C-dots). The electropolymn. of C-dots and (11-pyrrolyl-1-yl-undecyl) triethylammonium tetrafluoroborate (A2) enabled immobilization of the hydrophilic C-dots on the surface of glassy carbon electrode (GCE) perfectly, while the excellent cond. of polypyrrole was exploited to accelerate electron transfer between them. The Fe(CN)63-/4- can expeditiously convert the C-dots and S2O82- to C-dot.bul.- and SO4.bul.-, resp. High yields of the excited state C-dots (C-dots*) were obtained, and a ∼ 10-fold ECL amplification was realized. The C-dots* obtained through the recombination of electron-injected and hole-injected processes may be impeded due to the interference of GSH to K2S2O8. Therefore, the constructed sensor for GSH showed a detection limit down to 54.3 nM (S/N = 3) and a wide linear range from 0.1-1.0 $μ$M with a correlation coeff. of 0.997. [on SciFinder(R)]
Références
- Titre
- Ferrocyanide-Ferricyanide Redox Couple Induced Electrochemiluminescence Amplification of Carbon Dots for Ultrasensitive Sensing of Glutathione.
- Type de publication
- Article de revue
- Année de publication
- 2015
- Auteurs
- Niu, Wen-Jun, Zhu Rong-Hui, Cosnier Serge, Zhang Xue-Ji, and Shan Dan.
- Revue
- Anal. Chem. (Washington, DC, United States)
- Volume
- 87
- Pagination
- 11150–11156
- ISSN
- 0003-2700
Soumis le 12 avril 2018