Expedient Approach to Chiral Cyclobutanones: Asymmetric Synthesis of Cyclobut-G

An efficient one-pot asymmetric synthesis of cyclobutanones from chiral enol ethers is described. The approach is illustrated with alkyl- and functionalized alkyl-substituted enol ethers (nine examples). A new enantioselective synthesis of cyclobut-G (Lobucavir) could thus be achieved.

Références

Titre
Expedient Approach to Chiral Cyclobutanones: Asymmetric Synthesis of Cyclobut-G
Type de publication
Article de revue
Année de publication
2008
Revue
Organic Letters
Volume
10
Pagination
821–824
Soumis le 2 octobre 2018