Département de chimie moléculaire

The 1st example is reported of immobilization of a complex of the title type in thin polymeric films deposited on an electrode surface. Poly[(L)2MnIII(O)2MnIV(L)2]3+ films were prepd. by electropolymn. of the corresponding monomeric complexes contg. bipyridine ligand L having a pyrrole group as a substituent. The electrochem. behavior of these films was investigated in MeCN and in aq. soln. [on SciFinder(R)]