Electrochemically Driven Intramolecular Ring Closure of a Linear Hexapyrrole.

[24]Hexaphyrin(1.0.1.0.0.0) I was electrochem. synthesized in good yield starting from a linear hexapyrrolic precursor II. This straightforward approach provides an efficient "green" alternative to the reported chem. synthesis, which requires the use of trifluoroacetic acid as the solvent and toxic chromium(VI) salts as the oxidant. [on SciFinder(R)]

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Titre
Electrochemically Driven Intramolecular Ring Closure of a Linear Hexapyrrole.
Type de publication
Article de revue
Année de publication
2008
Revue
Org. Lett.
Volume
10
Pagination
425–428
ISSN
1523-7060
Soumis le 12 avril 2018