Electrochemically Driven Intramolecular Ring Closure of a Linear Hexapyrrole.
[24]Hexaphyrin(1.0.1.0.0.0) I was electrochem. synthesized in good yield starting from a linear hexapyrrolic precursor II. This straightforward approach provides an efficient "green" alternative to the reported chem. synthesis, which requires the use of trifluoroacetic acid as the solvent and toxic chromium(VI) salts as the oxidant. [on SciFinder(R)]
Références
- Titre
- Electrochemically Driven Intramolecular Ring Closure of a Linear Hexapyrrole.
- Type de publication
- Article de revue
- Année de publication
- 2008
- Auteurs
- Iordache, Adriana, Melfi Patricia, Bucher Christophe, Buda Mihai, Moutet Jean-Claude, and Sessler Jonathan L.
- Revue
- Org. Lett.
- Volume
- 10
- Pagination
- 425–428
- ISSN
- 1523-7060
Soumis le 12 avril 2018